Literature DB >> 22775535

Can zinc really exist in its oxidation state +III?

Tobias Schlöder1, Martin Kaupp, Sebastian Riedel.   

Abstract

Very recently, a thermochemically stable Zn(III) complex has been predicted by Samanta and Jena (J. Am. Chem. Soc. 2012, 134, 8400-8403). In contrast to their conclusions we show here by quantum chemical calculations that (a) Zn(AuF(6))(3) is not a thermochemically feasible compound, and (b) even if it could be made, it would not represent a Zn(III) oxidation state by any valid definition.

Entities:  

Year:  2012        PMID： 22775535     DOI： 10.1021/ja3052409

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

1.  Zinc of unsuspected worth.

Authors:  Anders Lennartson
Journal:  Nat Chem       Date:  2014-02       Impact factor: 24.427

2.  Formation of environmentally persistent free radicals (EPFRs) on ZnO at room temperature: Implications for the fundamental model of EPFR generation.

Authors:  Matthew C Patterson; Mark F DiTusa; Cheri A McFerrin; R L Kurtz; Randall W Hall; E D Poliakoff; P T Sprunger
Journal:  Chem Phys Lett       Date:  2016-12-31       Impact factor: 2.328

Review 3.  Understanding Periodic and Non-periodic Chemistry in Periodic Tables.

Authors:  Changsu Cao; René E Vernon; W H Eugen Schwarz; Jun Li
Journal:  Front Chem       Date:  2021-01-06       Impact factor: 5.221

4.  Recent Advances in the Synthesis, Characterization and Application of Zn+-containing Heterogeneous Catalysts.

Authors:  Guangbo Chen; Yufei Zhao; Lu Shang; Geoffrey I N Waterhouse; Xiaofeng Kang; Li-Zhu Wu; Chen-Ho Tung; Tierui Zhang
Journal:  Adv Sci (Weinh)       Date:  2016-02-03       Impact factor: 16.806

5.  One Dimensional Coordination Polymer of Zn(II) for Developing Multifunctional Nanoparticles.

Authors:  Rashmi A Agarwal
Journal:  Sci Rep       Date:  2017-10-16       Impact factor: 4.379
  5 in total

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