Literature DB >> 22772394

Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes.

Hajime Ito1, Yuko Horita, Eiji Yamamoto.   

Abstract

The regio- and diastereoselective silaboration of aromatic alkenes with a silylboron compound proceeds in the presence of a catalytic amount of potassium tert-butoxide, providing a complementary method to the corresponding transition metal-catalyzed reactions.

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Year:  2012        PMID： 22772394     DOI： 10.1039/c2cc32778c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Catalytic Enantioselective Synthesis of anti-Vicinal Silylboronates by Conjunctive Cross-Coupling.

Authors:  Yan Meng; Ziyin Kong; James P Morken
Journal:  Angew Chem Int Ed Engl       Date:  2020-03-19       Impact factor: 15.336

2.  Catalytic Carbo- and Aminoboration of Alkenyl Carbonyl Compounds via Five- and Six-Membered Palladacycles.

Authors:  Zhen Liu; Hui-Qi Ni; Tian Zeng; Keary M Engle
Journal:  J Am Chem Soc       Date:  2018-02-07       Impact factor: 15.419

3.  Boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides with silylborane and an alkoxy base: expanded scope and mechanistic studies.

Authors:  Eiji Yamamoto; Satoshi Ukigai; Hajime Ito
Journal:  Chem Sci       Date:  2015-03-02       Impact factor: 9.825

4.  Stereospecific and Chemoselective Copper-Catalyzed Deaminative Silylation of Benzylic Ammonium Triflates.

Authors:  Jonas Scharfbier; Benjamin M Gross; Martin Oestreich
Journal:  Angew Chem Int Ed Engl       Date:  2019-12-04       Impact factor: 15.336

5.  Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes.

Authors:  Aurora López; Alejandro Parra; Carlos Jarava-Barrera; Mariola Tortosa
Journal:  Chem Commun (Camb)       Date:  2015-12-28       Impact factor: 6.222
  5 in total

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