Literature DB >> 22763579

Diels-Alder cycloaddition of acetylene gas to a polycyclic aromatic hydrocarbon bay region.

Eric H Fort1, Matthew S Jeffreys, Lawrence T Scott.   

Abstract

The direct conversion of a polycyclic aromatic hydrocarbon bay region to a new, unsubstituted benzene ring by Diels-Alder cycloaddition of acetylene gas is reported for the first time. At 140 °C in dimethylformamide, under 1.8 atm pressure of acetylene gas, 7,14-dimesitylbisanthene is slowly converted to 7,14-dimesitylbenzo[ghi]bisanthene (21% conversion in 48 h).

Entities:  

Year:  2012        PMID： 22763579     DOI： 10.1039/c2cc33885h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Chirality-controlled synthesis of single-wall carbon nanotubes using vapour-phase epitaxy.

Authors:  Jia Liu; Chuan Wang; Xiaomin Tu; Bilu Liu; Liang Chen; Ming Zheng; Chongwu Zhou
Journal:  Nat Commun       Date:  2012-11-13       Impact factor: 14.919

2.  Initiation of carbon nanotube growth by well-defined carbon nanorings.

Authors:  Haruka Omachi; Takuya Nakayama; Eri Takahashi; Yasutomo Segawa; Kenichiro Itami
Journal:  Nat Chem       Date:  2013-05-26       Impact factor: 24.427

3.  Synthesis and photophysical properties of biphenyl and terphenyl arylene-ethynylene macrocycles.

Authors:  Andrew L Korich; Ian A McBee; Jonathan C Bennion; Jenna I Gifford; Thomas S Hughes
Journal:  J Org Chem       Date:  2014-02-07       Impact factor: 4.354

4.  Reversal of Clar's Aromatic-Sextet Rule in Ultrashort Single-End-Capped [5,5] Carbon Nanotubes.

Authors:  Guglielmo Monaco; Emeritus Lawrence T Scott; Riccardo Zanasi
Journal:  ChemistryOpen       Date:  2020-05-27       Impact factor: 2.911

5.  Towards pi-extended cycloparaphenylenes as seeds for CNT growth: investigating strain relieving ring-openings and rearrangements.

Authors:  Thomas J Sisto; Lev N Zakharov; Brittany M White; Ramesh Jasti
Journal:  Chem Sci       Date:  2016-02-18       Impact factor: 9.825

Review 6.  Diels-Alder Cycloaddition to the Bay Region of Perylene and Its Derivatives as an Attractive Strategy for PAH Core Expansion: Theoretical and Practical Aspects.

Authors:  Aneta Kurpanik; Marek Matussek; Piotr Lodowski; Grażyna Szafraniec-Gorol; Michał Krompiec; Stanisław Krompiec
Journal:  Molecules       Date:  2020-11-17       Impact factor: 4.411
  6 in total

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