Literature DB >> 22741596

Catalytic carbon-carbon σ-bond hydrogenation with water catalyzed by rhodium porphyrins.

Ching Tat To1, Kwong Shing Choi, Kin Shing Chan.   

Abstract

The catalytic carbon-carbon σ-bond activation and hydrogenation of [2.2]paracyclophane with water in a neutral reaction medium is demonstrated. The hydrogen from water is transferred to the hydrocarbon to furnish hydrogen enrichment in good yields.

Entities:  

Year:  2012        PMID： 22741596     DOI： 10.1021/ja3047415

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  2 in total

1.  Direct activation of relatively unstrained carbon-carbon bonds in homogeneous systems.

Authors:  Alpay Dermenci; Jotham W Coe; Guangbin Dong
Journal:  Org Chem Front       Date:  2014-03-27       Impact factor: 5.281

2.  "Broken-hearted" carbon bowl via electron shuttle reaction: energetics and electron coupling.

Authors:  Gabrielle A Leith; Allison M Rice; Brandon J Yarbrough; Preecha Kittikhunnatham; Abhijai Mathur; Nicholas A Morris; Megan J Francis; Anna A Berseneva; Poonam Dhull; Richard D Adams; M Victoria Bobo; Aaron A Vannucci; Mark D Smith; Sophya Garashchuk; Natalia B Shustova
Journal:  Chem Sci       Date:  2021-04-08       Impact factor: 9.825
  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.