| Literature DB >> 22740313 |
Michael R Harpham1, Son C Nguyen, Zongrui Hou, Jeffrey C Grossman, Charles B Harris, Michael W Mara, Andrew B Stickrath, Yosuke Kanai, Alexie M Kolpak, Donghwa Lee, Di-Jia Liu, Justin P Lomont, Kasper Moth-Poulsen, Nikolai Vinokurov, Lin X Chen, K Peter C Vollhardt.
Abstract
Caught in the light: The fulvalene diruthenium complex shown on the left side of the picture captures sun light, causing initial Ru-Ru bond rupture to furnish a long-lived triplet biradical of syn configuration. This species requires thermal activation to reach a crossing point (middle) into the singlet manifold on route to its thermal storage isomer on the right through the anti biradical.Entities:
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Year: 2012 PMID： 22740313 DOI： 10.1002/anie.201202952
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336