Literature DB >> 22740244

Oxidative dimerization of aromatic amines using tBuOI: entry to unsymmetric aromatic azo compounds.

Youhei Takeda1, Sota Okumura, Satoshi Minakata.   

Abstract

It's all the hype: An oxidative dimerization reaction of aromatic amines utilizing tert-butyl hypoiodite (tBuOI) under mild reaction conditions leads to aromatic azo compounds. The method allows access to unsymmetric aromatic azo compounds, which are difficult to prepare by conventional synthetic methods, in a selective manner.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID: 22740244     DOI: 10.1002/anie.201202786

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  8 in total

1.  Synthesis of Azobenzenes Using N-Chlorosuccinimide and 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU).

Authors:  Alford Antoine John; Qing Lin
Journal:  J Org Chem       Date:  2017-09-07       Impact factor: 4.354

2.  Facile Cu(I)-catalyzed oxidative coupling of anilines to azo compounds and hydrazines with diaziridinone under mild conditions.

Authors:  Yingguang Zhu; Yian Shi
Journal:  Org Lett       Date:  2013-04-01       Impact factor: 6.005

3.  Microwave-assisted rapid and sustainable synthesis of unsymmetrical azo dyes by coupling of nitroarenes with aniline derivatives.

Authors:  Ankit Thakuri; Mainak Banerjee; Amrita Chatterjee
Journal:  iScience       Date:  2022-05-31

4.  One-step Conversion of Levulinic Acid to Succinic Acid Using I2/t-BuOK System: The Iodoform Reaction Revisited.

Authors:  Ryosuke Kawasumi; Shodai Narita; Kazunori Miyamoto; Ken-Ichi Tominaga; Ryo Takita; Masanobu Uchiyama
Journal:  Sci Rep       Date:  2017-12-21       Impact factor: 4.379

5.  Synthesis of mono-functionalized S-diazocines via intramolecular Baeyer-Mills reactions.

Authors:  Miriam Schehr; Daniel Hugenbusch; Tobias Moje; Christian Näther; Rainer Herges
Journal:  Beilstein J Org Chem       Date:  2018-11-07       Impact factor: 2.883

6.  Synthesis of Bis-β-Diketonate Lanthanide Complexes with an Azobenzene Bridge and Studies of Their Reversible Photo/Thermal Isomerization Properties.

Authors:  Cai-Ye Fu; Lu Chen; Xuan Wang; Li-Rong Lin
Journal:  ACS Omega       Date:  2019-09-09

7.  Direct Oxidative Azo Coupling of Anilines Using a Self-Assembled Flower-like CuCo2O4 Material as a Catalyst under Aerobic Conditions.

Authors:  Ashok Raj Patel; Geetika Patel; Gurupada Maity; Shiv P Patel; Sumantra Bhattacharya; Anjaneyulu Putta; Subhash Banerjee
Journal:  ACS Omega       Date:  2020-11-17

8.  Oxidative Dehydrogenation of Hydrazobenzenes toward Azo Compounds Catalyzed by tert-Butyl Nitrite in EtOH.

Authors:  Zhi-Qiang Wang; Jiang-Xi Yu; Shan-Qin Bai; Bang Liu; Cheng-Yong Wang; Jin-Heng Li
Journal:  ACS Omega       Date:  2020-10-29
  8 in total

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