Literature DB >> 22739786

Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins.

Wangdong Zeng1, Byung Sun Lee, Young Mo Sung, Kuo-Wei Huang, Yuan Li, Dongho Kim, Jishan Wu.   

Abstract

4-tert-Butylphenyl-substituted and fused quinoidal porphyrins 1 and 2 are prepared for the first time. They show (1) intense one-photon absorption in the far-red/near-infrared region, (2) enhanced two-photon absorption compared with aromatic porphyrin monomers, and (3) amphoteric redox behavior. Their geometry and electronic structure are studied by DFT calculations.

Entities:  

Year:  2012        PMID: 22739786     DOI: 10.1039/c2cc33728b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  An unusual [4 + 2] fusion strategy to forge meso-N/O-heteroarene-fused (quinoidal) porphyrins with intense near-infrared Q-bands.

Authors:  Chengming Li; Lei Zhu; Wenbo Liang; Rongchuan Su; Jiangliang Yin; Yanmei Hu; Yu Lan; Di Wu; Jingsong You
Journal:  Chem Sci       Date:  2019-06-17       Impact factor: 9.825

  1 in total

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