Literature DB >> 22735620

A spin crossover ferrous complex with ordered magnetic ferric anions.

Olivier Roubeau1, Marco Evangelisti, Eva Natividad.   

Abstract

The first tetrahaloferrate spin crossover compound, [Fe(Metz)(6)](FeBr(4))(2) (Metz = 1-methyltetrazole), is reported. The FeBr(4)(-) ions form ferromagnetically coupled 1D stacks and exhibit an antiferromagnetic order at 2.2 K, which coexists with the gradual spin crossover centred at 165 K.

Entities:  

Year:  2012        PMID: 22735620     DOI: 10.1039/c2cc33709f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Switchable slow relaxation of magnetization in the native low temperature phase of a cooperative spin-crossover compound.

Authors:  A Urtizberea; O Roubeau
Journal:  Chem Sci       Date:  2016-12-19       Impact factor: 9.825

  1 in total

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