Literature DB >> 22730344

A vanadyl complex grafted to periodic mesoporous organosilica: a green catalyst for selective hydroxylation of benzene to phenol.

Parijat Borah1, Xing Ma, Kim Truc Nguyen, Yanli Zhao.   

Abstract

Selective benzene hydroxylation: A periodic mesoporous organosilica embedded with a vanadyl(IV) acetylacetonate complex has been synthesized through a co-condensation method. This system is a catalyst for direct hydroxylation of benzene to phenol, presenting a selectivity of 100 % towards the phenol formation as well as an excellent catalytic recyclability (see scheme).
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID: 22730344     DOI: 10.1002/anie.201203275

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  11 in total

Review 1.  Recent advanced development of metal-loaded mesoporous organosilicas as catalytic nanoreactors.

Authors:  Yucang Liang
Journal:  Nanoscale Adv       Date:  2021-10-22

2.  Hydroxylation of Benzene via C-H Activation Using Bimetallic CuAg@g-C3N4.

Authors:  Sanny Verma; R B Nasir Baig; Mallikarjuna N Nadagouda; Rajender S Varma
Journal:  ACS Sustain Chem Eng       Date:  2017       Impact factor: 8.198

3.  A bio-catalytically driven Janus mesoporous silica cluster motor with magnetic guidance.

Authors:  Xing Ma; Samuel Sanchez
Journal:  Chem Commun (Camb)       Date:  2015-03-28       Impact factor: 6.222

4.  Photocatalytic oxidation of benzene to phenol using dioxygen as an oxygen source and water as an electron source in the presence of a cobalt catalyst.

Authors:  Ji Won Han; Jieun Jung; Yong-Min Lee; Wonwoo Nam; Shunichi Fukuzumi
Journal:  Chem Sci       Date:  2017-08-21       Impact factor: 9.825

5.  Immediate hydroxylation of arenes to phenols via V-containing all-silica ZSM-22 zeolite triggered non-radical mechanism.

Authors:  Yu Zhou; Zhipan Ma; Junjie Tang; Ning Yan; Yonghua Du; Shibo Xi; Kai Wang; Wei Zhang; Haimeng Wen; Jun Wang
Journal:  Nat Commun       Date:  2018-07-26       Impact factor: 14.919

6.  A nickel nanoparticle engineered CoFe2O4/SiO2-NH2@carboxamide composite as a novel scaffold for the oxidation of sulfides and oxidative coupling of thiols.

Authors:  Mina Zohrevandi; Roya Mozafari; Mohammad Ghadermazi
Journal:  RSC Adv       Date:  2021-04-20       Impact factor: 3.361

7.  A new iron-based metal-organic framework with enhancing catalysis activity for benzene hydroxylation.

Authors:  Thach N Tu; Hue T T Nguyen; Huong T D Nguyen; My V Nguyen; Trinh D Nguyen; Nhung Thi Tran; Kwon Taek Lim
Journal:  RSC Adv       Date:  2019-05-29       Impact factor: 3.361

8.  Synthesis of (E)-2-(1H-tetrazole-5-yl)-3-phenylacrylenenitrile derivatives catalyzed by new ZnO nanoparticles embedded in a thermally stable magnetic periodic mesoporous organosilica under green conditions.

Authors:  Sajedeh Safapoor; Mohammad G Dekamin; Arezoo Akbari; M Reza Naimi-Jamal
Journal:  Sci Rep       Date:  2022-06-24       Impact factor: 4.996

9.  One-Step Selective Hydroxylation of Benzene to Phenol with Hydrogen Peroxide Catalysed by Copper Complexes Incorporated into Mesoporous Silica-Alumina.

Authors:  Mihoko Yamada; Kenneth D Karlin; Shunichi Fukuzumi
Journal:  Chem Sci       Date:  2016-01-05       Impact factor: 9.825

10.  Near-IR squaraine dye-loaded gated periodic mesoporous organosilica for photo-oxidation of phenol in a continuous-flow device.

Authors:  Parijat Borah; Sivaramapanicker Sreejith; Palapuravan Anees; Nishanth Venugopal Menon; Yuejun Kang; Ayyappanpillai Ajayaghosh; Yanli Zhao
Journal:  Sci Adv       Date:  2015-09-11       Impact factor: 14.136

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