Literature DB >> 22730058

Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination.

Yu-Lun Huang1, Duan-Yen Lu, Hsien-Cheng Yu, Jen-Shiang K Yu, Chia-Wei Hsu, Ting-Shen Kuo, Gene-Hsiang Lee, Yu Wang, Yi-Chou Tsai.   

Abstract

Give me five! Terdentate 2,6-diamidopyridyl ligands were used to stabilize the Cr-Cr quintuple bond and have made it possible to isolate and characterize not only the Cr-Cr quintuple-bonded complex, but also the mixed-valent intermediates (Cr(I) and Cr(II)), which are important species in the formation of type I quintuple-bonded complexes.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID: 22730058     DOI: 10.1002/anie.201202337

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  2 in total

1.  Pushing the Limits of Delta Bonding in Metal-Chromium Complexes with Redox Changes and Metal Swapping.

Authors:  Reed J Eisenhart; P Alex Rudd; Nora Planas; David W Boyce; Rebecca K Carlson; William B Tolman; Eckhard Bill; Laura Gagliardi; Connie C Lu
Journal:  Inorg Chem       Date:  2015-07-13       Impact factor: 5.165

2.  A bis(amido) ligand set that supports two-coordinate chromium in the +1, +2, and +3 oxidation states.

Authors:  Irene C Cai; Michael I Lipschutz; T Don Tilley
Journal:  Chem Commun (Camb)       Date:  2014-11-07       Impact factor: 6.222

  2 in total

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