Literature DB >> 22724899

Activation of H2O2 by chiral confined Brønsted acids: a highly enantioselective catalytic sulfoxidation.

Saihu Liao1, Ilija Čorić, Qinggang Wang, Benjamin List.   

Abstract

Confined chiral Brønsted acids are shown to catalyze asymmetric oxidations of sulfides to sulfoxides with hydrogen peroxide. The wide generality and high enantioselectivity of the developed method compare even to the best metal-based systems and suggest utility in other asymmetric oxidations.

Entities:  

Year:  2012        PMID： 22724899     DOI： 10.1021/ja3035637

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  12 in total

Review 1.  Asymmetric ion-pairing catalysis.

Authors:  Katrien Brak; Eric N Jacobsen
Journal:  Angew Chem Int Ed Engl       Date:  2012-11-28       Impact factor: 15.336

2.  The effect of nano confinement on the C-h activation and its corresponding structure-activity relationship.

Authors:  Jing Shao; Linghua Yuan; Xingbang Hu; Youting Wu; Zhibing Zhang
Journal:  Sci Rep       Date:  2014-11-27       Impact factor: 4.379

3.  Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation.

Authors:  Lili Zong; Chao Wang; Adhitya Mangala Putra Moeljadi; Xinyi Ye; Rakesh Ganguly; Yongxin Li; Hajime Hirao; Choon-Hong Tan
Journal:  Nat Commun       Date:  2016-11-21       Impact factor: 14.919

4.  Sixteen isostructural phosphonate metal-organic frameworks with controlled Lewis acidity and chemical stability for asymmetric catalysis.

Authors:  Xu Chen; Yongwu Peng; Xing Han; Yan Liu; Xiaochao Lin; Yong Cui
Journal:  Nat Commun       Date:  2017-12-19       Impact factor: 14.919

5.  Selecting Chiral BINOL-Derived Phosphoric Acid Catalysts: General Model To Identify Steric Features Essential for Enantioselectivity.

Authors:  Jolene P Reid; Jonathan M Goodman
Journal:  Chemistry       Date:  2017-09-14       Impact factor: 5.236

6.  Unveiling the Delicate Balance of Steric and Dispersion Interactions in Organocatalysis Using High-Level Computational Methods.

Authors:  Diana Yepes; Frank Neese; Benjamin List; Giovanni Bistoni
Journal:  J Am Chem Soc       Date:  2020-02-07       Impact factor: 15.419

7.  Internal acidity scale and reactivity evaluation of chiral phosphoric acids with different 3,3'-substituents in Brønsted acid catalysis.

Authors:  Kerstin Rothermel; Maxime Melikian; Johnny Hioe; Julian Greindl; Johannes Gramüller; Matej Žabka; Nils Sorgenfrei; Thomas Hausler; Fabio Morana; Ruth M Gschwind
Journal:  Chem Sci       Date:  2019-09-06       Impact factor: 9.825

8.  Modern Stereoselective Synthesis of Chiral Sulfinyl Compounds.

Authors:  Elżbieta Wojaczyńska; Jacek Wojaczyński
Journal:  Chem Rev       Date:  2020-04-29       Impact factor: 60.622

9.  Visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition.

Authors:  Cong Ye; Yanbin Zhang; Aishun Ding; Yong Hu; Hao Guo
Journal:  Sci Rep       Date:  2018-02-02       Impact factor: 4.379

10.  Enantioseparation, Stereochemical Assignment and Chiral Recognition Mechanism of Sulfoxide-Containing Drugs.

Authors:  Fei Xiong; Bei-Bei Yang; Jie Zhang; Li Li
Journal:  Molecules       Date:  2018-10-18       Impact factor: 4.411
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