Literature DB >> 22714095

Structural investigations into the deactivation pathway of the CO2 reduction electrocatalyst Re(bpy)(CO)3Cl.

Eric E Benson1, Clifford P Kubiak.   

Abstract

We report a series of complexes synthesized from the chemical reduction of the fac-tricarbonyl complex Re(bpy)(CO)(3)Cl. Synthesis and characterization of [Re(bpy)(CO)(3)](2), [Re(bpy)(CO)(3)](2)(-), and Re(bpy)(CO)(3)(-) are presented. The Re(bpy)(CO)(3)(-) anion has long been postulated as the active species that reacts with carbon dioxide in the electrochemical reduction of CO(2).

Entities:  

Year:  2012        PMID： 22714095     DOI： 10.1039/c2cc32617e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  8 in total

1.  Reduction of CO2 using a Rhenium Bipyridine Complex Containing Ancillary BODIPY Moieties.

Authors:  Justin J Teesdale; Allen J Pistner; Glenn P A Yap; Ying-Zhong Ma; Daniel A Lutterman; Joel Rosenthal
Journal:  Catal Today       Date:  2014-04-15       Impact factor: 6.766

2.  Synthesis, Spectroscopy, and Electrochemistry of (α-Diimine)M(CO)3Br, M = Mn, Re, Complexes: Ligands Isoelectronic to Bipyridyl Show Differences in CO2 Reduction.

Authors:  Matthew V Vollmer; Charles W Machan; Melissa L Clark; William E Antholine; Jay Agarwal; Henry F Schaefer; Clifford P Kubiak; Justin R Walensky
Journal:  Organometallics       Date:  2014-09-09       Impact factor: 3.876

3.  Bio-inspired CO2 reduction by a rhenium tricarbonyl bipyridine-based catalyst appended to amino acids and peptidic platforms: incorporating proton relays and hydrogen-bonding functional groups.

Authors:  S A Chabolla; C W Machan; J Yin; E A Dellamary; S Sahu; N C Gianneschi; M K Gilson; F A Tezcan; C P Kubiak
Journal:  Faraday Discuss       Date:  2017-06-02       Impact factor: 4.008

4.  Improving the photocatalytic reduction of CO2 to CO through immobilisation of a molecular Re catalyst on TiO2.

Authors:  Christopher D Windle; Ernest Pastor; Anna Reynal; Adrian C Whitwood; Yana Vaynzof; James R Durrant; Robin N Perutz; Erwin Reisner
Journal:  Chemistry       Date:  2015-01-29       Impact factor: 5.236

5.  Synergistic interaction of Re complex and amine functionalized multiple ligands in metal-organic frameworks for conversion of carbon dioxide.

Authors:  Un Jin Ryu; Sang Jun Kim; Hyung-Kyu Lim; Hyungjun Kim; Kyung Min Choi; Jeung Ku Kang
Journal:  Sci Rep       Date:  2017-04-04       Impact factor: 4.379

6.  Electronic structure analysis of electrochemical CO2 reduction by iron-porphyrins reveals basic requirements for design of catalysts bearing non-innocent ligands.

Authors:  Maxime Tarrago; Shengfa Ye; Frank Neese
Journal:  Chem Sci       Date:  2022-06-29       Impact factor: 9.969

7.  Comparison of rhenium-porphyrin dyads for CO2 photoreduction: photocatalytic studies and charge separation dynamics studied by time-resolved IR spectroscopy.

Authors:  Christopher D Windle; Michael W George; Robin N Perutz; Peter A Summers; Xue Zhong Sun; Adrian C Whitwood
Journal:  Chem Sci       Date:  2015-08-20       Impact factor: 9.825

8.  A stable covalent organic framework for photocatalytic carbon dioxide reduction.

Authors:  Zhiwei Fu; Xiaoyan Wang; Adrian M Gardner; Xue Wang; Samantha Y Chong; Gaia Neri; Alexander J Cowan; Lunjie Liu; Xiaobo Li; Anastasia Vogel; Rob Clowes; Matthew Bilton; Linjiang Chen; Reiner Sebastian Sprick; Andrew I Cooper
Journal:  Chem Sci       Date:  2019-11-21       Impact factor: 9.825
  8 in total

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