Literature DB >> 22711684

Chemoselective transfer hydrogenation to nitroarenes mediated by cubane-type Mo3S4 cluster catalysts.

Iván Sorribes1, Gerrit Wienhöfer, Cristian Vicent, Kathrin Junge, Rosa Llusar, Matthias Beller.   

Abstract

Chemoselective cubes: Cubane-type [Mo(3)S(4)X(3)(dmpe)(3)](+) clusters (dmpe = 1,2-(bis)dimethylphosphinoethane), in combination with an azeotropic 5:2 mixture of HCOOH and NEt(3) as the reducing agent, act as selective cluster catalysts (X = H) or precatalysts (X = Cl) for the transfer hydrogenation of functionalized nitroarenes, without the formation of hazardous hydroxylamines.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID： 22711684     DOI： 10.1002/anie.201202584

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  7 in total

1.  CO-free, aqueous mediated, instant and selective reduction of nitrobenzene via robustly stable chalcogen stabilised iron carbonyl clusters (Fe3E2(CO)9, E = S, Se, Te).

Authors:  Charu Sharma; Avinash Kumar Srivastava; Aditi Soni; Sangeeta Kumari; Raj Kumar Joshi
Journal:  RSC Adv       Date:  2020-09-01       Impact factor: 4.036

2.  Transitioning organic synthesis from organic solvents to water. What's your E Factor?

Authors:  Bruce H Lipshutz; Subir Ghorai
Journal:  Green Chem       Date:  2014-08-01       Impact factor: 10.182

3.  Chemoselective reductions of nitroaromatics in water at room temperature.

Authors:  Sean M Kelly; Bruce H Lipshutz
Journal:  Org Lett       Date:  2013-12-16       Impact factor: 6.005

4.  Synthesis of flower-like magnetite nanoassembly: Application in the efficient reduction of nitroarenes.

Authors:  Kasibhatta J Datta; Anuj K Rathi; Pawan Kumar; Josef Kaslik; Ivo Medrik; Vaclav Ranc; Rajender S Varma; Radek Zboril; Manoj B Gawande
Journal:  Sci Rep       Date:  2017-09-14       Impact factor: 4.379

5.  High performance of a cobalt-nitrogen complex for the reduction and reductive coupling of nitro compounds into amines and their derivatives.

Authors:  Peng Zhou; Liang Jiang; Fan Wang; Kejian Deng; Kangle Lv; Zehui Zhang
Journal:  Sci Adv       Date:  2017-02-17       Impact factor: 14.136

6.  Molecularly Engineering Defective Basal Planes in Molybdenum Sulfide for the Direct Synthesis of Benzimidazoles by Reductive Coupling of Dinitroarenes with Aldehydes.

Authors:  Miriam Rodenes; Francisco Gonell; Santiago Martín; Avelino Corma; Iván Sorribes
Journal:  JACS Au       Date:  2022-02-09

7.  Nitrogen-doped graphene-activated metallic nanoparticle-incorporated ordered mesoporous carbon nanocomposites for the hydrogenation of nitroarenes.

Authors:  Haigen Huang; Xueguang Wang; Yao Sheng; Chenju Chen; Xiujing Zou; Xingfu Shang; Xionggang Lu
Journal:  RSC Adv       Date:  2018-02-26       Impact factor: 3.361
  7 in total

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