Literature DB >> 22708637

Difluoro(trimethylsilyl)acetonitrile: synthesis and fluoroalkylation reactions.

Mikhail D Kosobokov1, Alexander D Dilman, Vitalij V Levin, Marina I Struchkova.   

Abstract

A new silicon reagent, difluoro(trimethylsilyl)acetonitrile, was prepared by insertion of difluorocarbene into silyl cyanide. The obtained silane served as a good cyanodifluoromethylating reagent toward aldehydes, N-tosylimines, N-alkylimines, and enamines under basic or acidic conditions.

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Year:  2012        PMID： 22708637     DOI： 10.1021/jo301094b

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  Deoxygenative gem-difluoroolefination of carbonyl compounds with (chlorodifluoromethyl)trimethylsilane and triphenylphosphine.

Authors:  Fei Wang; Lingchun Li; Chuanfa Ni; Jinbo Hu
Journal:  Beilstein J Org Chem       Date:  2014-02-06       Impact factor: 2.883

2.  Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers.

Authors:  Vyacheslav I Supranovich; Vitalij V Levin; Alexander D Dilman
Journal:  Beilstein J Org Chem       Date:  2020-06-29       Impact factor: 2.883

3.  Insertion of Carbenes into Deprotonated nido-Undecaborane, B11H13(2-).

Authors:  Jacek Pecyna; Igor Rončević; Josef Michl
Journal:  Molecules       Date:  2019-10-21       Impact factor: 4.411
  3 in total

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