Literature DB >> 22705974

Protodecarboxylation of benzoic acids under radical conditions.

Sangwon Seo1, John B Taylor, Michael F Greaney.   

Abstract

A new approach to protodecarboxylation is described that enhances the substrate scope for benzoic acids. The reaction uses oxidative radical conditions to decarboxylate a variety of acids in acetonitrile.

Entities:  

Year:  2012        PMID： 22705974     DOI： 10.1039/c2cc33306f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  8 in total

1.  Skeletal Torsion Tunneling and Methyl Internal Rotation: The Coupled Large Amplitude Motions in Phenyl Acetate.

Authors:  Lynn Ferres; Luca Evangelisti; Assimo Maris; Sonia Melandri; Walther Caminati; Wolfgang Stahl; Ha Vinh Lam Nguyen
Journal:  Molecules       Date:  2022-04-23       Impact factor: 4.927

2.  Mild aromatic palladium-catalyzed protodecarboxylation: kinetic assessment of the decarboxylative palladation and the protodepalladation steps.

Authors:  Joshua S Dickstein; John M Curto; Osvaldo Gutierrez; Carol A Mulrooney; Marisa C Kozlowski
Journal:  J Org Chem       Date:  2013-04-29       Impact factor: 4.354

3.  Contemporary methods for generation of aryl radicals.

Authors:  Nikita Kvasovs; Vladimir Gevorgyan
Journal:  Chem Soc Rev       Date:  2021-03-01       Impact factor: 54.564

Review 4.  Recent Progress in Decarboxylative Oxidative Cross-Coupling for Biaryl Synthesis.

Authors:  Gregory J P Perry; Igor Larrosa
Journal:  European J Org Chem       Date:  2017-04-26

5.  Mild, visible light-mediated decarboxylation of aryl carboxylic acids to access aryl radicals.

Authors:  L Candish; M Freitag; T Gensch; F Glorius
Journal:  Chem Sci       Date:  2017-02-27       Impact factor: 9.825

6.  Transition-Metal-Free Decarboxylative Iodination: New Routes for Decarboxylative Oxidative Cross-Couplings.

Authors:  Gregory J P Perry; Jacob M Quibell; Adyasha Panigrahi; Igor Larrosa
Journal:  J Am Chem Soc       Date:  2017-08-08       Impact factor: 15.419

7.  Copper(I) Catalyzed Decarboxylative Synthesis of Diareno[a,e]cyclooctatetraenes.

Authors:  Magdalena Tasić; Albert Ruiz-Soriano; Daniel Strand
Journal:  J Org Chem       Date:  2022-05-19       Impact factor: 4.198

8.  Organophotoredox/palladium dual catalytic decarboxylative Csp3-Csp3 coupling of carboxylic acids and π-electrophiles.

Authors:  Kaitie C Cartwright; Jon A Tunge
Journal:  Chem Sci       Date:  2020-07-16       Impact factor: 9.825
  8 in total

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