Literature DB >> 22702395

Copper-catalyzed aerobic spirocyclization of biaryl-N-H-imines via 1,4-aminooxygenation of benzene rings.

Ya Lin Tnay1, Cheng Chen, Yi Yuan Chua, Line Zhang, Shunsuke Chiba.   

Abstract

A synthetic method of azaspirocyclohexadienones has been developed through copper-catalyzed aerobic spirocyclization of biaryl-N-H-imines prepared by the reaction of biarylcarbonitriles and Grignard reagents.

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Year:  2012        PMID： 22702395     DOI： 10.1021/ol301583y

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

Review 1.  Aerobic copper-catalyzed organic reactions.

Authors:  Scott E Allen; Ryan R Walvoord; Rosaura Padilla-Salinas; Marisa C Kozlowski
Journal:  Chem Rev       Date:  2013-06-20       Impact factor: 60.622

Review 2.  Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations.

Authors:  Rachel Trammell; Khashayar Rajabimoghadam; Isaac Garcia-Bosch
Journal:  Chem Rev       Date:  2019-01-30       Impact factor: 60.622

3.  Cobalt complexes of the chelating dicarboxylate ligand "esp": a paddlewheel-type dimer and a heptanuclear coordination cluster.

Authors:  Ryan J Pakula; John F Berry
Journal:  Dalton Trans       Date:  2018-10-09       Impact factor: 4.390

4.  Copper-catalyzed aerobic aliphatic C-H oxygenation with hydroperoxides.

Authors:  Pei Chui Too; Ya Lin Tnay; Shunsuke Chiba
Journal:  Beilstein J Org Chem       Date:  2013-06-25       Impact factor: 2.883

5.  Copper-catalyzed aerobic radical C-C bond cleavage of N-H ketimines.

Authors:  Ya Lin Tnay; Gim Yean Ang; Shunsuke Chiba
Journal:  Beilstein J Org Chem       Date:  2015-10-19       Impact factor: 2.883
  5 in total

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