| Literature DB >> 22697555 |
A K Khitrin1, Jiadi Xu, Ayyalusamy Ramamoorthy.
Abstract
Quantum-mechanical evolution of systems with periodic time-modulated Hamiltonians is often described by effective interactions. Such average Hamiltonians, calculated as few terms of an expansion in powers of the interaction, are sometimes difficult to relate to experimental observations. We propose a frequency-domain approach to this problem, which offers certain advantages and produces an approximate solution for the density matrix, better linked to measurable quantities. The formalism is suitable for calculating the intensities of narrowed spectral peaks. Fast magic-angle-spinning NMR spectra of solids are used to experimentally illustrate the method.Mesh:
Year: 2012 PMID: 22697555 PMCID: PMC3377367 DOI: 10.1063/1.4723682
Source DB: PubMed Journal: J Chem Phys ISSN: 0021-9606 Impact factor: 3.488