Literature DB >> 22696242

Deoxygenative reduction of carbon dioxide to methane, toluene, and diphenylmethane with [Et2Al]+ as catalyst.

Manish Khandelwal1, Rudolf J Wehmschulte.   

Abstract

The strong Lewis acid [Et(2)Al](+) catalyzes the reduction of carbon dioxide with hydrosilanes under mild conditions to methane. In benzene solution, the side products toluene and diphenylmethane are also obtained through Lewis acid catalyzed benzene alkylation by reaction intermediates.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 22696242     DOI： 10.1002/anie.201201282

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  12 in total

1.  Insight into catalytic reduction of CO2 to methane with silanes using Brookhart's cationic Ir(iii) pincer complex.

Authors:  Shaoqin Fang; Hongcai Chen; Haiyan Wei
Journal:  RSC Adv       Date:  2018-03-02       Impact factor: 4.036

2.  Isolable fluorinated triphenylmethyl cation salts of [HCB11Cl11]-: demonstration of remarkable hydride affinity.

Authors:  S Olivia Gunther; Chun-I Lee; Ellen Song; Nattamai Bhuvanesh; Oleg V Ozerov
Journal:  Chem Sci       Date:  2022-04-04       Impact factor: 9.969

Review 3.  Activation of Si-H and B-H bonds by Lewis acidic transition metals and p-block elements: same, but different.

Authors:  Pablo Ríos; Amor Rodríguez; Salvador Conejero
Journal:  Chem Sci       Date:  2022-06-06       Impact factor: 9.969

4.  Carbon dioxide reduction to methane and coupling with acetylene to form propylene catalyzed by remodeled nitrogenase.

Authors:  Zhi-Yong Yang; Vivian R Moure; Dennis R Dean; Lance C Seefeldt
Journal:  Proc Natl Acad Sci U S A       Date:  2012-11-12       Impact factor: 11.205

5.  Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO2 in the Presence of Silylhalides.

Authors:  Tongtong Wang; Maotong Xu; Andrew R Jupp; Zheng-Wang Qu; Stefan Grimme; Douglas W Stephan
Journal:  Angew Chem Int Ed Engl       Date:  2021-11-03       Impact factor: 16.823

6.  Heterogeneous reduction of carbon dioxide by hydride-terminated silicon nanocrystals.

Authors:  Wei Sun; Chenxi Qian; Le He; Kulbir Kaur Ghuman; Annabelle P Y Wong; Jia Jia; Abdinoor A Jelle; Paul G O'Brien; Laura M Reyes; Thomas E Wood; Amr S Helmy; Charles A Mims; Chandra Veer Singh; Geoffrey A Ozin
Journal:  Nat Commun       Date:  2016-08-23       Impact factor: 14.919

7.  Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO2, and hydrosilane catalyzed by 1,3,2-diazaphospholene?

Authors:  Yu Lu; Zhong-Hua Gao; Xiang-Yu Chen; Jiandong Guo; Zheyuan Liu; Yanfeng Dang; Song Ye; Zhi-Xiang Wang
Journal:  Chem Sci       Date:  2017-09-11       Impact factor: 9.825

8.  Transition-Metal-Free Cleavage of CO.

Authors:  Marc Devillard; Bas de Bruin; Maxime A Siegler; J I van der Vlugt
Journal:  Chemistry       Date:  2017-09-07       Impact factor: 5.236

9.  Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion.

Authors:  Lukas Omann; Bimal Pudasaini; Elisabeth Irran; Hendrik F T Klare; Mu-Hyun Baik; Martin Oestreich
Journal:  Chem Sci       Date:  2018-05-21       Impact factor: 9.825

10.  Catalytic CO2 Reduction with Boron- and Aluminum Hydrides.

Authors:  Daniel Franz; Christian Jandl; Claire Stark; Shigeyoshi Inoue
Journal:  ChemCatChem       Date:  2019-09-30       Impact factor: 5.686
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