Literature DB >> 22694293

Efficient and highly aldehyde selective Wacker oxidation.

Peili Teo1, Zachary K Wickens, Guangbin Dong, Robert H Grubbs.   

Abstract

A method for efficient and aldehyde-selective Wacker oxidation of aryl-substituted olefins using PdCl(2)(MeCN)(2), 1,4-benzoquinone, and t-BuOH in air is described. Up to a 96% yield of aldehyde can be obtained, and up to 99% selectivity can be achieved with styrene-related substrates.

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Year:  2012        PMID： 22694293     DOI： 10.1021/ol301240g

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  9 in total

1.  Formal Anti-Markovnikov Hydroamination of Terminal Olefins.

Authors:  Sarah M Bronner; Robert H Grubbs
Journal:  Chem Sci       Date:  2014-01       Impact factor: 9.825

2.  Direct Access to β-Fluorinated Aldehydes by Nitrite-Modified Wacker Oxidation.

Authors:  Crystal K Chu; Daniel T Ziegler; Brian Carr; Zachary K Wickens; Robert H Grubbs
Journal:  Angew Chem Int Ed Engl       Date:  2016-05-25       Impact factor: 15.336

3.  Concise Total Syntheses of (+)-Haplocidine and (+)-Haplocine via Late-Stage Oxidation of (+)-Fendleridine Derivatives.

Authors:  Kolby L White; Mohammad Movassaghi
Journal:  J Am Chem Soc       Date:  2016-08-26       Impact factor: 15.419

4.  Iron-Catalyzed Wacker-type Oxidation of Olefins at Room Temperature with 1,3-Diketones or Neocuproine as Ligands*.

Authors:  Florian Puls; Philipp Linke; Olga Kataeva; Hans-Joachim Knölker
Journal:  Angew Chem Int Ed Engl       Date:  2021-05-14       Impact factor: 15.336

5.  Graphene oxide-iridium nanocatalyst for the transformation of benzylic alcohols into carbonyl compounds.

Authors:  Tsun-Ren Chen; Yi-Sheng Lin; Yu-Xiang Wang; Wen-Jen Lee; Kelvin H-C Chen; Jhy-Der Chen
Journal:  RSC Adv       Date:  2020-01-27       Impact factor: 4.036

6.  Manganese vacancy-confined single-atom Ag in cryptomelane nanorods for efficient Wacker oxidation of styrene derivatives.

Authors:  Hongling Yang; Xun Zhang; Yi Yu; Zheng Chen; Qinggang Liu; Yang Li; Weng-Chon Cheong; Dongdong Qi; Zewen Zhuang; Qing Peng; Xin Chen; Hai Xiao; Chen Chen; Yadong Li
Journal:  Chem Sci       Date:  2021-03-16       Impact factor: 9.825

7.  Molecular structures of cdc2-like kinases in complex with a new inhibitor chemotype.

Authors:  Anne Walter; Apirat Chaikuad; Renate Helmer; Nadège Loaëc; Lutz Preu; Ingo Ott; Stefan Knapp; Laurent Meijer; Conrad Kunick
Journal:  PLoS One       Date:  2018-05-03       Impact factor: 3.240

Review 8.  Application of Coordination Compounds with Transition Metal Ions in the Chemical Industry-A Review.

Authors:  Jacek Malinowski; Dominika Zych; Dagmara Jacewicz; Barbara Gawdzik; Joanna Drzeżdżon
Journal:  Int J Mol Sci       Date:  2020-07-30       Impact factor: 5.923

9.  Catalytic Isohypsic-Redox Sequences for the Rapid Generation of Csp3 -Containing Heterocycles.

Authors:  Craig D Smith; David Phillips; Alina Tirla; David J France
Journal:  Chemistry       Date:  2018-11-02       Impact factor: 5.236
  9 in total

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