Literature DB >> 22692514

A tetrameric neptunyl(v) cluster supported by a Schiff base ligand.

Roy Copping1, Victor Mougel, Christophe Den Auwer, Claude Berthon, Philippe Moisy, Marinella Mazzanti.   

Abstract

The first tetrameric cation-cation neptunyl(v) cluster, [{NpO(2)(salen)}(4)(μ(8)-K)(2)][K(18C6)Py](2), has been synthesized in non-aqueous solution from the reaction of [(NpO(2)Py(5))(KI(2)Py(2))](n) with K(2)salen and its structure determined in the solid state and in solution where the complex retains its tetrameric form.

Entities:  

Year:  2012        PMID: 22692514     DOI: 10.1039/c2dt31072d

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  2 in total

Review 1.  Oligonuclear Actinoid Complexes with Schiff Bases as Ligands-Older Achievements and Recent Progress.

Authors:  Sokratis T Tsantis; Demetrios I Tzimopoulos; Malgorzata Holynska; Spyros P Perlepes
Journal:  Int J Mol Sci       Date:  2020-01-15       Impact factor: 5.923

2.  Creation of an unexpected plane of enhanced covalency in cerium(III) and berkelium(III) terpyridyl complexes.

Authors:  Alyssa N Gaiser; Cristian Celis-Barros; Frankie D White; Maria J Beltran-Leiva; Joseph M Sperling; Sahan R Salpage; Todd N Poe; Daniela Gomez Martinez; Tian Jian; Nikki J Wolford; Nathaniel J Jones; Amanda J Ritz; Robert A Lazenby; John K Gibson; Ryan E Baumbach; Dayán Páez-Hernández; Michael L Neidig; Thomas E Albrecht-Schönzart
Journal:  Nat Commun       Date:  2021-12-10       Impact factor: 14.919

  2 in total

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