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Literature DB >> 22674896

Formation and characterization of gaseous adducts of carbon dioxide to magnesium, (CO2)MgX- (X=OH, Cl, Br).

Héloïse Dossmann Soldi-Lose¹, Carlos Afonso, Denis Lesage, Jean-Claude Tabet, Einar Uggerud.

Abstract

A good fix: the structure and chemical reactivity of a reduced form of CO(2) bonded to magnesium, XMg(η(2)-O(2)C)(-), is reported. Upon reaction with water it loses CO, while it adds CH(3) upon reaction with alkyl halides, thereby signifying nucleophilicity of the carbon atom in XMg(η(2)-O(2)C)(-) in S(N)2 reactions.

Entities: Chemical

Mesh：

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Year: 2012 PMID： 22674896 DOI： 10.1002/anie.201108477

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

6 in total

1. Carbon-carbon bond formation in the reaction of hydrated carbon dioxide radical anions with 3-butyn-1-ol.

Authors: Andreas Herburger; Milan Ončák; Erik Barwa; Christian van der Linde; Martin K Beyer
Journal: Int J Mass Spectrom Date: 2018-10-12 Impact factor: 1.986

2. Carbon Dioxide Activation at Metal Centers: Evolution of Charge Transfer from Mg ^.+ to CO₂ in [MgCO₂ (H₂ O)_n ]^.+ , n=0-8.

Authors: Erik Barwa; Tobias F Pascher; Milan Ončák; Christian van der Linde; Martin K Beyer
Journal: Angew Chem Int Ed Engl Date: 2020-03-12 Impact factor: 15.336

3. Release of Formic Acid from Copper Formate: Hydride, Proton-Coupled Electron and Hydrogen Atom Transfer All Play their Role.

Authors: Tobias F Pascher; Milan Ončák; Christian van der Linde; Martin K Beyer
Journal: Chemphyschem Date: 2019-04-29 Impact factor: 3.102

4. CO₂/O₂ Exchange in Magnesium-Water Clusters Mg⁺(H₂O) _n.

Authors: Erik Barwa; Milan Ončák; Tobias F Pascher; Thomas Taxer; Christian van der Linde; Martin K Beyer
Journal: J Phys Chem A Date: 2018-12-19 Impact factor: 2.781

5. Periodic Trends Manifested through Gas-Phase Generation of Anions Such as [AlH₄]^-, [GaH₄]^-, [InH₄]^-, [SrH₃]^-, [BaH₃]^-, [Ba(0)(η²-O₂CH)₁]^-, [Pb(0)H]^-, [Bi(I)H₂]^-, and Bi^- from Formates.

Authors: Zhaoyu Zheng; Julius Pavlov; Yang Wei; Yong Zhang; Athula B Attygalle
Journal: ACS Omega Date: 2018-03-23

6. Infrared Multiple Photon Dissociation Spectroscopy of Hydrated Cobalt Anions Doped with Carbon Dioxide CoCO₂ (H₂ O)_n ^- , n=1-10, in the C-O Stretch Region.

Authors: Erik Barwa; Milan Ončák; Tobias F Pascher; Andreas Herburger; Christian van der Linde; Martin K Beyer
Journal: Chemistry Date: 2020-01-16 Impact factor: 5.236

6 in total

Formation and characterization of gaseous adducts of carbon dioxide to magnesium, (CO2)MgX- (X=OH, Cl, Br).

1. Carbon-carbon bond formation in the reaction of hydrated carbon dioxide radical anions with 3-butyn-1-ol.

2. Carbon Dioxide Activation at Metal Centers: Evolution of Charge Transfer from Mg .+ to CO2 in [MgCO2 (H2 O)n ].+ , n=0-8.

3. Release of Formic Acid from Copper Formate: Hydride, Proton-Coupled Electron and Hydrogen Atom Transfer All Play their Role.

4. CO2/O2 Exchange in Magnesium-Water Clusters Mg+(H2O) n.

5. Periodic Trends Manifested through Gas-Phase Generation of Anions Such as [AlH4]-, [GaH4]-, [InH4]-, [SrH3]-, [BaH3]-, [Ba(0)(η2-O2CH)1]-, [Pb(0)H]-, [Bi(I)H2]-, and Bi- from Formates.

6. Infrared Multiple Photon Dissociation Spectroscopy of Hydrated Cobalt Anions Doped with Carbon Dioxide CoCO2 (H2 O)n - , n=1-10, in the C-O Stretch Region.

2. Carbon Dioxide Activation at Metal Centers: Evolution of Charge Transfer from Mg ^.+ to CO₂ in [MgCO₂ (H₂ O)_n ]^.+ , n=0-8.

4. CO₂/O₂ Exchange in Magnesium-Water Clusters Mg⁺(H₂O) _n.

5. Periodic Trends Manifested through Gas-Phase Generation of Anions Such as [AlH₄]^-, [GaH₄]^-, [InH₄]^-, [SrH₃]^-, [BaH₃]^-, [Ba(0)(η²-O₂CH)₁]^-, [Pb(0)H]^-, [Bi(I)H₂]^-, and Bi^- from Formates.

6. Infrared Multiple Photon Dissociation Spectroscopy of Hydrated Cobalt Anions Doped with Carbon Dioxide CoCO₂ (H₂ O)_n ^- , n=1-10, in the C-O Stretch Region.