Literature DB >> 22670563

Designing higher surface area metal-organic frameworks: are triple bonds better than phenyls?

Omar K Farha1, Christopher E Wilmer, Ibrahim Eryazici, Brad G Hauser, Philip A Parilla, Kevin O'Neill, Amy A Sarjeant, SonBinh T Nguyen, Randall Q Snurr, Joseph T Hupp.   

Abstract

We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.

Entities:  

Year:  2012        PMID： 22670563     DOI： 10.1021/ja302623w

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  8 in total

1.  Efficient biodiesel production from oleic and palmitic acid using a novel molybdenum metal-organic framework as efficient and reusable catalyst.

Authors:  Arash Ghorbani-Choghamarani; Zahra Taherinia; Yunes Abbasi Tyula
Journal:  Sci Rep       Date:  2022-06-20       Impact factor: 4.996

Review 2.  Grand Challenges and Future Opportunities for Metal-Organic Frameworks.

Authors:  Christopher H Hendon; Adam J Rieth; Maciej D Korzyński; Mircea Dincă
Journal:  ACS Cent Sci       Date:  2017-06-06       Impact factor: 14.553

3.  Chemical principles underpinning the performance of the metal-organic framework HKUST-1.

Authors:  Christopher H Hendon; Aron Walsh
Journal:  Chem Sci       Date:  2015-05-11       Impact factor: 9.825

4.  Reversed thermo-switchable molecular sieving membranes composed of two-dimensional metal-organic nanosheets for gas separation.

Authors:  Xuerui Wang; Chenglong Chi; Kang Zhang; Yuhong Qian; Krishna M Gupta; Zixi Kang; Jianwen Jiang; Dan Zhao
Journal:  Nat Commun       Date:  2017-02-16       Impact factor: 14.919

5.  Substituted 1,3,5-Triazine Hexacarboxylates as Potential Linkers for MOFs.

Authors:  Arne Klinkebiel; Ole Beyer; Ulrich Lüning
Journal:  Molecules       Date:  2019-09-25       Impact factor: 4.411

6.  Retrofitting metal-organic frameworks.

Authors:  Christian Schneider; David Bodesheim; Julian Keupp; Rochus Schmid; Gregor Kieslich
Journal:  Nat Commun       Date:  2019-10-29       Impact factor: 14.919

Review 7.  Synthesis and Biomedical Applications of Highly Porous Metal-Organic Frameworks.

Authors:  Ahmed Ahmed; Darragh McHugh; Constantina Papatriantafyllopoulou
Journal:  Molecules       Date:  2022-10-05       Impact factor: 4.927

8.  A rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO(2) and H(2) uptake capability.

Authors:  Xiao-Jun Wang; Pei-Zhou Li; Yifei Chen; Quan Zhang; Huacheng Zhang; Xiu Xiang Chan; Rakesh Ganguly; Yongxin Li; Jianwen Jiang; Yanli Zhao
Journal:  Sci Rep       Date:  2013-01-28       Impact factor: 4.379
  8 in total

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