Literature DB >> 22662328

Intermediates in the Rh-catalysed dehydrocoupling of phosphine-borane.

Miguel A Huertos1, Andrew S Weller.   

Abstract

Active species, product distributions and a suggested catalytic cycle are reported for the dehydrocoupling of the phosphine-borane H(3)B·P(t)Bu(2)H to give HP(t)Bu(2)BH(2)P(t)Bu(2)BH(3) using the [Rh(COD)(2)][BAr(F)(4)] pre-catalyst.

Entities:  

Year:  2012        PMID： 22662328     DOI： 10.1039/c2cc32696e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

Review 1.  Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials.

Authors:  Erin M Leitao; Titel Jurca; Ian Manners
Journal:  Nat Chem       Date:  2013-10       Impact factor: 24.427

2.  Effect of the phosphine steric and electronic profile on the Rh-promoted dehydrocoupling of phosphine-boranes.

Authors:  Thomas N Hooper; Miguel A Huertos; Titel Jurca; Sebastian D Pike; Andrew S Weller; Ian Manners
Journal:  Inorg Chem       Date:  2014-03-11       Impact factor: 5.165

3.  Metal-Free Addition/Head-to-Tail Polymerization of Transient Phosphinoboranes, RPH-BH2: A Route to Poly(alkylphosphinoboranes).

Authors:  Christian Marquardt; Titel Jurca; Karl-Christian Schwan; Andreas Stauber; Alexander V Virovets; George R Whittell; Ian Manners; Manfred Scheer
Journal:  Angew Chem Int Ed Engl       Date:  2015-10-02       Impact factor: 15.336

4.  Dehydrocoupling of phosphine-boranes using the [RhCp*Me(PMe3)(CH2Cl2)][BArF4] precatalyst: stoichiometric and catalytic studies.

Authors:  Thomas N Hooper; Andrew S Weller; Nicholas A Beattie; Stuart A Macgregor
Journal:  Chem Sci       Date:  2015-12-21       Impact factor: 9.825
  4 in total

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