Literature DB >> 22653656

Bioconversion of iodoacetophenones by marine fungi.

Lenilson C Rocha1, Rodrigo F Luiz, Isac G Rosset, Cristiano Raminelli, Mirna H R Seleghim, Lara Durães Sette, André L M Porto.   

Abstract

Nine marine fungi (Aspergillus sclerotiorum CBMAI 849, Aspergillus sydowii Ce19, Beauveria felina CBMAI 738, Mucor racemosus CBMAI 847, Penicillium citrinum CBMAI 1186, Penicillium miczynskii Ce16, P. miczynskii Gc5, Penicillium oxalicum CBMAI 1185, and Trichoderma sp. Gc1) catalyzed the asymmetric bioconversion of iodoacetophenones 1-3 to corresponding iodophenylethanols 6-8. All the marine fungi produced exclusively (S)-ortho-iodophenylethanol 6 and (S)-meta-iodophenylethanol 7 in accordance to the Prelog rule. B. felina CBMAI 738, P. miczynskii Gc5, P. oxalicum CBMAI 1185, and Trichoderma sp. Gc1 produced (R)-para-iodophenylethanol 8 as product anti-Prelog. The bioconversion of para-iodoacetophenone 3 with whole cells of P. oxalicum CBMAI 1185 showed competitive reduction-oxidation reactions.

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Year:  2012        PMID： 22653656     DOI： 10.1007/s10126-012-9463-2

Source DB:  PubMed          Journal:  Mar Biotechnol (NY)        ISSN： 1436-2228            Impact factor:   3.619


  7 in total

1.  Use of experimental design for the optimization of the production of new secondary metabolites by two Penicillium species.

Authors:  Eli F Pimenta; Aline M Vita-Marques; Aristeu Tininis; Mirna H R Seleghim; Lara D Sette; Katyuscya Veloso; Antonio G Ferreira; David E Williams; Brian O Patrick; Doralyn S Dalisay; Raymond J Andersen; Roberto G S Berlinck
Journal:  J Nat Prod       Date:  2010-11-05       Impact factor: 4.050

2.  Chemoenzymatic synthesis of alpha-hydroxy-beta-methyl-gamma-hydroxy esters: role of the keto-enol equilibrium to control the stereoselective hydrogenation in a key step.

Authors:  Cíntia D F Milagre; Humberto M S Milagre; Paulo J S Moran; J Augusto R Rodrigues
Journal:  J Org Chem       Date:  2010-03-05       Impact factor: 4.354

3.  Marine fungi Aspergillus sydowii and Trichoderma sp. catalyze the hydrolysis of benzyl glycidyl ether.

Authors:  Mariana Provedel Martins; Ana Maria Mouad; Letícia Boschini; Mirna Helena Regali Seleghim; Lara Durães Sette; André Luiz Meleiro Porto
Journal:  Mar Biotechnol (NY)       Date:  2010-06-12       Impact factor: 3.619

Review 4.  Marine metagenomics: new tools for the study and exploitation of marine microbial metabolism.

Authors:  Jonathan Kennedy; Burkhardt Flemer; Stephen A Jackson; David P H Lejon; John P Morrissey; Fergal O'Gara; Alan D W Dobson
Journal:  Mar Drugs       Date:  2010-03-15       Impact factor: 5.118

5.  Biotransformation of α-bromoacetophenones by the marine fungus Aspergillus sydowii.

Authors:  Lenilson Coutinho Rocha; Hercules Vicente Ferreira; Eli Fernando Pimenta; Roberto Gomes Souza Berlinck; Maria Olímpia Oliveira Rezende; Maria Diva Landgraf; Mirna Helena Regali Seleghim; Lara Durães Sette; André Luiz Meleiro Porto
Journal:  Mar Biotechnol (NY)       Date:  2009-11-27       Impact factor: 3.619

6.  Bioreduction of alpha-chloroacetophenone by whole cells of marine fungi.

Authors:  Lenilson C Rocha; Hercules V Ferreira; Eli F Pimenta; Roberto G S Berlinck; Mirna H R Seleghim; Darci C D Javaroti; Lara D Sette; Rafaella C Bonugli; André L M Porto
Journal:  Biotechnol Lett       Date:  2009-06-03       Impact factor: 2.461

Review 7.  Recent advances in the biocatalytic reduction of ketones and oxidation of sec-alcohols.

Authors:  Wolfgang Kroutil; Harald Mang; Klaus Edegger; Kurt Faber
Journal:  Curr Opin Chem Biol       Date:  2004-04       Impact factor: 8.822
  7 in total
  2 in total

1.  Biotransformation of methylphenylacetonitriles by Brazilian marine fungal strain Aspergillus sydowii CBMAI 934: eco-friendly reactions.

Authors:  Julieta Rangel de Oliveira; Mirna Helena Regali Seleghim; André Luiz Meleiro Porto
Journal:  Mar Biotechnol (NY)       Date:  2013-09-22       Impact factor: 3.619

2.  Induction, expression and characterisation of laccase genes from the marine-derived fungal strains Nigrospora sp. CBMAI 1328 and Arthopyrenia sp. CBMAI 1330.

Authors:  Michel Rodrigo Zambrano Passarini; Cristiane Angelica Ottoni; Cledir Santos; Nelson Lima; Lara Durães Sette
Journal:  AMB Express       Date:  2015-03-11       Impact factor: 3.298
  2 in total

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