Literature DB >> 22647071

Access to C(sp3)-C(sp2) and C(sp2)-C(sp2) bond formation via sequential intermolecular carbopalladation of multiple carbon-carbon bonds.

Yanmei Wen1, Liangbin Huang, Huanfeng Jiang.   

Abstract

A synthetic strategy of 4-benzyl-substituted 1,3-butadiene derivatives through Pd-catalyzed three-component coupling reaction of benzyl chlorides, alkynes, and monosubstituted alkenes is described. This tandem coupling reaction forms a C(sp(3))-C(sp(2)) bond and a C(sp(2))-C(sp(2)) bond sequentially in a single-step operation.

Entities:  

Year:  2012        PMID： 22647071     DOI： 10.1021/jo300662x

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  Highly Stereoselective Synthesis of Tetrasubstituted Acyclic All-Carbon Olefins via Enol Tosylation and Suzuki-Miyaura Coupling.

Authors:  Beryl X Li; Diane N Le; Kyle A Mack; Andrew McClory; Ngiap-Kie Lim; Theresa Cravillion; Scott Savage; Chong Han; David B Collum; Haiming Zhang; Francis Gosselin
Journal:  J Am Chem Soc       Date:  2017-07-26       Impact factor: 15.419

2.  Sequential Insertion of Alkynes, Alkenes, and CO into the Pd-C Bond of ortho-Palladated Primary Phenethylamines: from η3-Allyl Complexes and Enlarged Palladacycles to Functionalized Arylalkylamines.

Authors:  José-Antonio García-López; María-José Oliva-Madrid; Delia Bautista; José Vicente; Isabel Saura-Llamas
Journal:  Organometallics       Date:  2021-01-29       Impact factor: 3.876

3.  Highly efficient synthesis of 3,4-diarylbutadiene sulfones using Heck-Matsuda reaction.

Authors:  Olga V Shurupova; Sergey A Rzhevskiy; Lidiya I Minaeva; Maxim A Topchiy; Andrey F Asachenko
Journal:  RSC Adv       Date:  2022-02-15       Impact factor: 3.361
  3 in total

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