Literature DB >> 22643822

Exploring the intermediates of photochemical CO2 reduction: reaction of Re(dmb)(CO)3 COOH with CO2.

Jay Agarwal1, Brian C Sanders, Etsuko Fujita, Henry F Schaefer, Todd C Harrop, James T Muckerman.   

Abstract

We have investigated the reaction of Re(dmb)(CO)(3)COOH with CO(2) using density functional theory, and propose a mechanism for the production of CO. This mechanism supports the role of Re(dmb)(CO)(3)COOH as a key intermediate in the formation of CO. Our new experimental work supports the proposed scheme.

Entities:  

Year:  2012        PMID： 22643822     DOI： 10.1039/c2cc32288a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Reduction of CO2 using a Rhenium Bipyridine Complex Containing Ancillary BODIPY Moieties.

Authors:  Justin J Teesdale; Allen J Pistner; Glenn P A Yap; Ying-Zhong Ma; Daniel A Lutterman; Joel Rosenthal
Journal:  Catal Today       Date:  2014-04-15       Impact factor: 6.766

2.  Photocatalytic Conversion of CO2 to CO using Rhenium Bipyridine Platforms Containing Ancillary Phenyl or BODIPY Moieties.

Authors:  Gabriel A Andrade; Allen J Pistner; Glenn P A Yap; Daniel A Lutterman; Joel Rosenthal
Journal:  ACS Catal       Date:  2013-08-02       Impact factor: 13.084

3.  Electron-transfer sensitization of H2 oxidation and CO2 reduction catalysts using a single chromophore.

Authors:  Nathan T La Porte; Davis B Moravec; Michael D Hopkins
Journal:  Proc Natl Acad Sci U S A       Date:  2014-06-24       Impact factor: 11.205

4.  Photochemical conversion of CO2 to CO by a Re complex: theoretical insights into the formation of CO and HCO3 - from an experimentally detected monoalkyl carbonate complex.

Authors:  Miho Isegawa; Akhilesh K Sharma
Journal:  RSC Adv       Date:  2021-11-24       Impact factor: 3.361

5.  Molecular Catalysts with Intramolecular Re-O Bond for Electrochemical Reduction of Carbon Dioxide.

Authors:  Laura Rotundo; Dmitry E Polyansky; Roberto Gobetto; David C Grills; Etsuko Fujita; Carlo Nervi; Gerald F Manbeck
Journal:  Inorg Chem       Date:  2020-08-17       Impact factor: 5.165
  5 in total

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