Literature DB >> 22643651

Reaction of carbon dioxide with a palladium-alkyl complex supported by a bis-NHC framework.

Piyal W G Ariyananda1, Glenn P A Yap, Joel Rosenthal.   

Abstract

The reactivity of a dimethyl palladium complex supported by a dicarbene chelate (MDC(Mes))PdMe(2) towards CO(2) has been investigated. In the presence of trace H(2)O, this reaction yields the corresponding methyl bicarbonate complex (MDC(Mes))PdMe(O(2)COH), which goes on to give the corresponding κ(2)-carbonato complex upon crystallization (MDC(Mes))Pd(CO(3)). This chemistry, as well as related protonolysis by acetic acid was monitored by a combination of techniques including React-IR spectroscopy.

Entities:  

Mesh：

Substances：

Year:  2012        PMID： 22643651      PMCID： PMC3443874          DOI： 10.1039/c2dt30676j

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  19 in total

1.  Transformation of carbon dioxide.

Authors:  Toshiyasu Sakakura; Jun-Chul Choi; Hiroyuki Yasuda
Journal:  Chem Rev       Date:  2007-06       Impact factor: 60.622

2.  A method for the synthesis of nickel(0) bis(carbene) complexes.

Authors:  Andreas A Danopoulos; David Pugh
Journal:  Dalton Trans       Date:  2008-01-07       Impact factor: 4.390

Review 3.  Chemical technologies for exploiting and recycling carbon dioxide into the value chain.

Authors:  Martina Peters; Burkhard Köhler; Wilhelm Kuckshinrichs; Walter Leitner; Peter Markewitz; Thomas E Müller
Journal:  ChemSusChem       Date:  2011-08-22       Impact factor: 8.928

4.  Direct observation of a carbonylation reaction relevant to CO/alkene copolymerization in a methylpalladium carbonyl complex containing a bis(N-heterocyclic carbene) ligand.

Authors:  Sri S Subramanium; Legrande M Slaughter
Journal:  Dalton Trans       Date:  2009-07-10       Impact factor: 4.390

5.  Insertion of CO2 into a palladium allyl bond and a Pd(II) catalysed carboxylation of allyl stannanes.

Authors:  Roger Johansson; Ola F Wendt
Journal:  Dalton Trans       Date:  2006-12-18       Impact factor: 4.390

6.  Organoplatinum(II) complexes containing chelating or bridging bis(N-heterocyclic carbene) ligands: formation of a platinum(II) carbonate complex by aerial CO2 fixation.

Authors:  Sirous Jamali; Dalibor Milić; Reza Kia; Zahra Mazloomi; Hallimeh Abdolahi
Journal:  Dalton Trans       Date:  2011-06-09       Impact factor: 4.390

Review 7.  Carbon dioxide recycling: emerging large-scale technologies with industrial potential.

Authors:  Elsje Alessandra Quadrelli; Gabriele Centi; Jean-Luc Duplan; Siglinda Perathoner
Journal:  ChemSusChem       Date:  2011-09-19       Impact factor: 8.928

Review 8.  Turning carbon dioxide into fuel.

Authors:  Z Jiang; T Xiao; V L Kuznetsov; P P Edwards
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2010-07-28       Impact factor: 4.226

9.  Palladium(I)-bridging allyl dimers for the catalytic functionalization of CO2.

Authors:  Damian P Hruszkewycz; Jianguo Wu; Nilay Hazari; Christopher D Incarvito
Journal:  J Am Chem Soc       Date:  2011-02-18       Impact factor: 15.419

10.  N-heterocyclic carbenes: a new concept in organometallic catalysis.

Authors:  Wolfgang A Herrmann
Journal:  Angew Chem Int Ed Engl       Date:  2002-04-15       Impact factor: 15.336
View more
  1 in total

1.  Ab Initio Density Functional Calculations and Infra-Red Study of CO Interaction with Pd Atoms on θ-Al2O3 (010) Surface.

Authors:  Chaitanya K Narula; Lawrence F Allard; Zili Wu
Journal:  Sci Rep       Date:  2017-07-24       Impact factor: 4.379
  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.