| Literature DB >> 22641477 |
Maxim N Sokolov1, Sergey A Adonin, Pavel A Abramov, Dmitry A Mainichev, Nina F Zakharchuk, Vladimir P Fedin.
Abstract
A sandwich-type rhodium polyoxotungstate with unprecedented tetrarhodium-oxo core Na(12)[(Rh(4)(μ(3)-O)(2)(H(2)O)(2))(H(2)W(9)O(33))(2)]·38H(2)O (1) was obtained by hydrothermal reaction of rhodium(II) acetate and sodium tungstate; crystal structure was determined by X-ray diffractometry and was confirmed by (183)W NMR data; 1 is active in electrocatalytic water oxidation.Entities:
Year: 2012 PMID： 22641477 DOI： 10.1039/c2cc31692g
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222