Literature DB >> 22621258

Iron-catalyzed 2-arylbenzoxazole formation from o-nitrophenols and benzylic alcohols.

Mingyue Wu1, Xiong Hu, Juan Liu, Yunfeng Liao, Guo-Jun Deng.   

Abstract

The iron-catalyzed 2-arylbenzoxazole formation from o-nitrophenols and benzylic alcohols using hydrogen transfer is described. Various 2-arylbenzoxazoles were selectively obtained in good to excellent yields. The reaction tolerated a wide range of functionalities. The alcohol oxidation, nitro reduction, condensation, and dehydrogenation were realized in a cascade without external reducing reagent and oxidant.

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Year:  2012        PMID: 22621258     DOI: 10.1021/ol300937z

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  One-step synthesis of azole- and benzazole-based sulfonamides in aqueous media.

Authors:  Hassan Zali-Boeini; Zhaleh Najafi; Bahareh Abtahi; Hajar Golshadi Ghaleshahi
Journal:  Mol Divers       Date:  2015-01-23       Impact factor: 2.943

2.  Iron-catalyzed one-pot synthesis of quinoxalines: transfer hydrogenative condensation of 2-nitroanilines with vicinal diols.

Authors:  Ramachandra Reddy Putta; Simin Chun; Seok Beom Lee; Junhwa Hong; Dong-Chan Oh; Suckchang Hong
Journal:  RSC Adv       Date:  2021-05-20       Impact factor: 3.361

  2 in total

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