6,6'-Dimeth-oxy-2,2'-[(E,E')-(2,4,6-trimethyl-1,3-phenyl-ene)bis-(nitrilo-methanylyl-idene)]diphenol chloro-form monosolvate.

In the title compound, C(25)H(26)N(2)O(4)·CHCl(3), the aromatic rings of the imino-methyl-6-meth-oxy-phenol fragments make dihedral angles of 58.33 (6) and 87.74 (6)° with the central benzene ring. The mol-ecular conformation is stabilized by intra-molecular O-H⋯N hydrogen bonds. In the crystal, an inter-molecular C-H⋯O hydrogen bond involving the chloro-form solvent mol-ecule is observed. The crystal packing is further stabilized by π-π stacking inter-actions [centroid-centroid distances = 3.739 (3)-3.776 (3) Å] between the benzene rings of centrosymmetrically related mol-ecules.

Related literature

For a related structure, see: Yamin et al. (2009 ▶). For the synthetic procedure, see: Hernández-Molina et al. (1997 ▶). For standard bond lengths, see: Allen et al. (1987 ▶).

Experimental

Crystal data

C25H26N2O4·CHCl3

M = 537.85

Triclinic,

a = 10.162 (2) Å

b = 10.486 (2) Å

c = 12.640 (3) Å

α = 99.315 (4)°

β = 93.140 (4)°

γ = 90.196 (4)°

V = 1327.0 (5) Å3

Z = 2

Mo Kα radiation

μ = 0.38 mm−1

T = 298 K

0.50 × 0.47 × 0.44 mm

Data collection

Bruker SMART APEX CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2000 ▶) T min = 0.833, T max = 0.851

14608 measured reflections

4947 independent reflections

3799 reflections with I > 2σ(I)

R int = 0.017

Refinement

R[F 2 > 2σ(F 2)] = 0.051

wR(F 2) = 0.150

S = 1.04

4947 reflections

329 parameters

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.42 e Å−3

Δρmin = −0.43 e Å−3

Data collection: SMART (Bruker, 2000 ▶); cell refinement: SAINT (Bruker, 2000 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL, PARST (Nardelli, 1995 ▶) and PLATON (Spek, 2009 ▶).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536812011531/rz2720sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536812011531/rz2720Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C25H26N2O4·CHCl3	Z = 2
Mr = 537.85	F(000) = 560
Triclinic, P1	Dx = 1.346 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 10.162 (2) Å	Cell parameters from 5967 reflections
b = 10.486 (2) Å	θ = 2.0–25.5°
c = 12.640 (3) Å	µ = 0.38 mm−1
α = 99.315 (4)°	T = 298 K
β = 93.140 (4)°	Block, colourless
γ = 90.196 (4)°	0.50 × 0.47 × 0.44 mm
V = 1327.0 (5) Å3

Bruker SMART APEX CCD area-detector diffractometer	4947 independent reflections
Radiation source: fine-focus sealed tube	3799 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.017
Detector resolution: 83.66 pixels mm-1	θmax = 25.5°, θmin = 2.0°
ω scan	h = −12→12
Absorption correction: multi-scan (SADABS; Bruker, 2000)	k = −12→12
Tmin = 0.833, Tmax = 0.851	l = −15→15
14608 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.051	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.150	H atoms treated by a mixture of independent and constrained refinement
S = 1.04	w = 1/[σ2(Fo2) + (0.0709P)2 + 0.542P] where P = (Fo2 + 2Fc2)/3
4947 reflections	(Δ/σ)max < 0.001
329 parameters	Δρmax = 0.42 e Å−3
0 restraints	Δρmin = −0.43 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Cl1	0.03110 (10)	0.62554 (11)	0.86722 (8)	0.1141 (4)
Cl2	0.27407 (11)	0.52065 (10)	0.93526 (9)	0.1134 (3)
Cl3	0.12916 (12)	0.69304 (10)	1.08602 (7)	0.1112 (4)
O1	0.66016 (19)	0.17533 (16)	0.16568 (15)	0.0666 (5)
O2	0.78095 (19)	0.01822 (19)	0.02179 (15)	0.0774 (5)
O3	0.24675 (16)	0.87363 (16)	0.38440 (18)	0.0742 (6)
O4	0.12149 (18)	1.08231 (16)	0.3545 (2)	0.0897 (7)
N1	0.47101 (18)	0.21937 (16)	0.29251 (15)	0.0518 (4)
N2	0.24295 (18)	0.62506 (16)	0.38954 (16)	0.0527 (4)
C1	0.4031 (2)	0.28405 (19)	0.47697 (18)	0.0500 (5)
C2	0.3505 (2)	0.3788 (2)	0.55115 (18)	0.0536 (5)
H2	0.3515	0.3665	0.6224	0.064*
C3	0.2966 (2)	0.4910 (2)	0.52441 (18)	0.0512 (5)
C4	0.2981 (2)	0.50847 (18)	0.41760 (18)	0.0473 (5)
C5	0.3573 (2)	0.42049 (19)	0.34071 (17)	0.0492 (5)
C6	0.4070 (2)	0.30635 (19)	0.37139 (18)	0.0474 (5)
C7	0.4551 (3)	0.1628 (2)	0.5135 (2)	0.0662 (6)
H7A	0.3897	0.0952	0.4967	0.099*
H7B	0.4750	0.1794	0.5896	0.099*
H7C	0.5336	0.1367	0.4774	0.099*
C8	0.2394 (3)	0.5905 (2)	0.6084 (2)	0.0705 (7)
H8A	0.1449	0.5873	0.5993	0.106*
H8B	0.2707	0.6749	0.6010	0.106*
H8C	0.2660	0.5726	0.6785	0.106*
C9	0.3669 (3)	0.4462 (2)	0.2278 (2)	0.0721 (7)
H9A	0.2897	0.4123	0.1851	0.108*
H9B	0.4437	0.4050	0.1977	0.108*
H9C	0.3735	0.5376	0.2283	0.108*
C10	0.4370 (2)	0.1001 (2)	0.26946 (18)	0.0520 (5)
H10	0.3665	0.0698	0.3027	0.062*
C11	0.5068 (2)	0.0109 (2)	0.19195 (18)	0.0515 (5)
C12	0.6140 (2)	0.0524 (2)	0.14253 (18)	0.0529 (5)
C13	0.6780 (2)	−0.0339 (2)	0.06563 (19)	0.0599 (6)
C14	0.6338 (3)	−0.1596 (2)	0.0417 (2)	0.0716 (7)
H14	0.6758	−0.2175	−0.0089	0.086*
C15	0.5280 (3)	−0.2015 (2)	0.0915 (2)	0.0767 (8)
H15	0.4998	−0.2872	0.0745	0.092*
C16	0.4642 (3)	−0.1179 (2)	0.1656 (2)	0.0655 (6)
H16	0.3927	−0.1467	0.1985	0.079*
C17	0.8454 (3)	−0.0624 (4)	−0.0602 (3)	0.1006 (11)
H17A	0.8850	−0.1334	−0.0315	0.151*
H17B	0.9125	−0.0134	−0.0870	0.151*
H17C	0.7824	−0.0949	−0.1177	0.151*
C18	0.1223 (2)	0.6255 (2)	0.36095 (18)	0.0513 (5)
H18	0.0749	0.5483	0.3533	0.062*
C19	0.0532 (2)	0.7410 (2)	0.33923 (17)	0.0498 (5)
C20	−0.0803 (2)	0.7342 (3)	0.3063 (2)	0.0689 (7)
H20	−0.1244	0.6549	0.2957	0.083*
C21	−0.1466 (3)	0.8424 (3)	0.2894 (3)	0.0801 (8)
H21	−0.2353	0.8364	0.2666	0.096*
C22	−0.0827 (3)	0.9608 (3)	0.3060 (2)	0.0720 (7)
H22	−0.1290	1.0346	0.2956	0.086*
C23	0.0486 (2)	0.9705 (2)	0.3378 (2)	0.0595 (6)
C24	0.1182 (2)	0.8603 (2)	0.35432 (18)	0.0499 (5)
C25	0.0571 (3)	1.1989 (3)	0.3692 (3)	0.0928 (10)
H25A	0.0083	1.2092	0.3040	0.139*
H25B	0.1205	1.2681	0.3880	0.139*
H25C	−0.0023	1.2005	0.4259	0.139*
C26	0.1719 (3)	0.6559 (3)	0.9533 (2)	0.0741 (7)
H26	0.2196	0.7299	0.9349	0.089*
H3	0.275 (3)	0.797 (4)	0.392 (3)	0.109 (11)*
H1	0.605 (3)	0.218 (3)	0.210 (3)	0.101 (11)*

	U11	U22	U33	U12	U13	U23
Cl1	0.1134 (7)	0.1233 (8)	0.0967 (6)	0.0259 (6)	−0.0080 (5)	−0.0049 (5)
Cl2	0.1231 (8)	0.1002 (7)	0.1177 (7)	0.0351 (6)	0.0131 (6)	0.0177 (5)
Cl3	0.1584 (9)	0.1091 (7)	0.0672 (5)	−0.0003 (6)	0.0309 (5)	0.0097 (4)
O1	0.0770 (12)	0.0468 (9)	0.0746 (11)	0.0004 (8)	0.0250 (9)	−0.0016 (8)
O2	0.0793 (12)	0.0798 (12)	0.0697 (11)	0.0162 (10)	0.0216 (9)	−0.0039 (9)
O3	0.0490 (9)	0.0427 (9)	0.1321 (17)	0.0056 (7)	−0.0044 (9)	0.0210 (10)
O4	0.0635 (11)	0.0417 (9)	0.167 (2)	0.0105 (8)	0.0093 (12)	0.0248 (11)
N1	0.0546 (10)	0.0388 (9)	0.0620 (11)	0.0110 (8)	0.0091 (8)	0.0065 (8)
N2	0.0534 (11)	0.0344 (9)	0.0710 (12)	0.0073 (7)	0.0058 (9)	0.0095 (8)
C1	0.0467 (11)	0.0418 (11)	0.0622 (13)	0.0061 (9)	0.0012 (10)	0.0108 (9)
C2	0.0590 (13)	0.0491 (12)	0.0537 (12)	0.0043 (10)	0.0039 (10)	0.0112 (10)
C3	0.0528 (12)	0.0405 (11)	0.0595 (13)	0.0037 (9)	0.0080 (10)	0.0035 (9)
C4	0.0465 (11)	0.0322 (10)	0.0632 (13)	0.0035 (8)	0.0039 (9)	0.0075 (9)
C5	0.0522 (12)	0.0391 (10)	0.0570 (12)	0.0042 (9)	0.0063 (9)	0.0086 (9)
C6	0.0442 (11)	0.0361 (10)	0.0611 (13)	0.0061 (8)	0.0058 (9)	0.0048 (9)
C7	0.0717 (16)	0.0554 (14)	0.0740 (16)	0.0197 (12)	−0.0027 (12)	0.0193 (12)
C8	0.0881 (18)	0.0522 (14)	0.0700 (16)	0.0146 (12)	0.0194 (14)	0.0012 (12)
C9	0.099 (2)	0.0565 (14)	0.0644 (15)	0.0228 (13)	0.0172 (14)	0.0164 (12)
C10	0.0503 (12)	0.0442 (12)	0.0611 (13)	0.0078 (9)	0.0026 (10)	0.0078 (10)
C11	0.0571 (13)	0.0389 (11)	0.0565 (12)	0.0099 (9)	−0.0030 (10)	0.0041 (9)
C12	0.0609 (13)	0.0429 (11)	0.0531 (12)	0.0129 (10)	−0.0018 (10)	0.0043 (9)
C13	0.0659 (15)	0.0569 (14)	0.0540 (13)	0.0201 (11)	−0.0001 (11)	0.0014 (10)
C14	0.0876 (19)	0.0573 (15)	0.0625 (15)	0.0236 (13)	−0.0011 (14)	−0.0115 (12)
C15	0.095 (2)	0.0425 (13)	0.0849 (19)	0.0075 (13)	−0.0076 (16)	−0.0082 (12)
C16	0.0721 (16)	0.0461 (13)	0.0753 (16)	0.0021 (11)	−0.0032 (13)	0.0034 (11)
C17	0.082 (2)	0.125 (3)	0.082 (2)	0.0240 (19)	0.0192 (16)	−0.0254 (19)
C18	0.0572 (13)	0.0373 (10)	0.0595 (13)	0.0008 (9)	0.0072 (10)	0.0066 (9)
C19	0.0520 (12)	0.0442 (11)	0.0544 (12)	0.0071 (9)	0.0059 (9)	0.0102 (9)
C20	0.0565 (14)	0.0592 (14)	0.0923 (19)	−0.0024 (11)	−0.0047 (13)	0.0196 (13)
C21	0.0532 (14)	0.0771 (18)	0.113 (2)	0.0059 (13)	−0.0115 (14)	0.0308 (16)
C22	0.0593 (15)	0.0619 (15)	0.101 (2)	0.0180 (12)	0.0056 (14)	0.0310 (14)
C23	0.0548 (13)	0.0452 (12)	0.0817 (16)	0.0100 (10)	0.0116 (11)	0.0177 (11)
C24	0.0452 (11)	0.0457 (11)	0.0603 (13)	0.0090 (9)	0.0083 (9)	0.0109 (9)
C25	0.086 (2)	0.0506 (15)	0.141 (3)	0.0160 (14)	0.0102 (19)	0.0142 (17)
C26	0.0911 (19)	0.0671 (16)	0.0665 (16)	−0.0008 (14)	0.0179 (14)	0.0136 (13)

Cl1—C26	1.745 (3)	C9—H9B	0.9600
Cl2—C26	1.753 (3)	C9—H9C	0.9600
Cl3—C26	1.738 (3)	C10—C11	1.457 (3)
O1—C12	1.351 (3)	C10—H10	0.9300
O1—H1	0.89 (4)	C11—C12	1.388 (3)
O2—C13	1.363 (3)	C11—C16	1.399 (3)
O2—C17	1.419 (3)	C12—C13	1.406 (3)
O3—C24	1.340 (3)	C13—C14	1.372 (4)
O3—H3	0.88 (4)	C14—C15	1.380 (4)
O4—C23	1.366 (3)	C14—H14	0.9300
O4—C25	1.379 (3)	C15—C16	1.368 (4)
N1—C10	1.280 (3)	C15—H15	0.9300
N1—C6	1.425 (3)	C16—H16	0.9300
N2—C18	1.259 (3)	C17—H17A	0.9600
N2—C4	1.435 (3)	C17—H17B	0.9600
C1—C2	1.381 (3)	C17—H17C	0.9600
C1—C6	1.394 (3)	C18—C19	1.458 (3)
C1—C7	1.509 (3)	C18—H18	0.9300
C2—C3	1.383 (3)	C19—C24	1.394 (3)
C2—H2	0.9300	C19—C20	1.395 (3)
C3—C4	1.392 (3)	C20—C21	1.362 (4)
C3—C8	1.505 (3)	C20—H20	0.9300
C4—C5	1.391 (3)	C21—C22	1.380 (4)
C5—C6	1.404 (3)	C21—H21	0.9300
C5—C9	1.503 (3)	C22—C23	1.370 (3)
C7—H7A	0.9600	C22—H22	0.9300
C7—H7B	0.9600	C23—C24	1.396 (3)
C7—H7C	0.9600	C25—H25A	0.9600
C8—H8A	0.9600	C25—H25B	0.9600
C8—H8B	0.9600	C25—H25C	0.9600
C8—H8C	0.9600	C26—H26	0.9800
C9—H9A	0.9600
C12—O1—H1	106 (2)	O2—C13—C14	126.2 (2)
C13—O2—C17	117.6 (2)	O2—C13—C12	114.9 (2)
C24—O3—H3	107 (2)	C14—C13—C12	118.9 (2)
C23—O4—C25	118.9 (2)	C13—C14—C15	121.0 (2)
C10—N1—C6	121.59 (19)	C13—C14—H14	119.5
C18—N2—C4	118.54 (18)	C15—C14—H14	119.5
C2—C1—C6	117.92 (19)	C16—C15—C14	120.5 (2)
C2—C1—C7	119.0 (2)	C16—C15—H15	119.7
C6—C1—C7	123.0 (2)	C14—C15—H15	119.7
C1—C2—C3	123.1 (2)	C15—C16—C11	119.9 (3)
C1—C2—H2	118.5	C15—C16—H16	120.0
C3—C2—H2	118.5	C11—C16—H16	120.0
C2—C3—C4	117.53 (19)	O2—C17—H17A	109.5
C2—C3—C8	120.8 (2)	O2—C17—H17B	109.5
C4—C3—C8	121.6 (2)	H17A—C17—H17B	109.5
C5—C4—C3	121.95 (18)	O2—C17—H17C	109.5
C5—C4—N2	120.19 (19)	H17A—C17—H17C	109.5
C3—C4—N2	117.76 (18)	H17B—C17—H17C	109.5
C4—C5—C6	118.1 (2)	N2—C18—C19	123.36 (19)
C4—C5—C9	121.06 (19)	N2—C18—H18	118.3
C6—C5—C9	120.87 (19)	C19—C18—H18	118.3
C1—C6—C5	121.22 (19)	C24—C19—C20	119.0 (2)
C1—C6—N1	121.34 (18)	C24—C19—C18	120.59 (19)
C5—C6—N1	117.24 (19)	C20—C19—C18	120.4 (2)
C1—C7—H7A	109.5	C21—C20—C19	120.7 (2)
C1—C7—H7B	109.5	C21—C20—H20	119.7
H7A—C7—H7B	109.5	C19—C20—H20	119.7
C1—C7—H7C	109.5	C20—C21—C22	120.3 (2)
H7A—C7—H7C	109.5	C20—C21—H21	119.9
H7B—C7—H7C	109.5	C22—C21—H21	119.9
C3—C8—H8A	109.5	C23—C22—C21	120.4 (2)
C3—C8—H8B	109.5	C23—C22—H22	119.8
H8A—C8—H8B	109.5	C21—C22—H22	119.8
C3—C8—H8C	109.5	O4—C23—C22	125.1 (2)
H8A—C8—H8C	109.5	O4—C23—C24	114.9 (2)
H8B—C8—H8C	109.5	C22—C23—C24	120.0 (2)
C5—C9—H9A	109.5	O3—C24—C19	122.20 (18)
C5—C9—H9B	109.5	O3—C24—C23	118.2 (2)
H9A—C9—H9B	109.5	C19—C24—C23	119.6 (2)
C5—C9—H9C	109.5	O4—C25—H25A	109.5
H9A—C9—H9C	109.5	O4—C25—H25B	109.5
H9B—C9—H9C	109.5	H25A—C25—H25B	109.5
N1—C10—C11	121.1 (2)	O4—C25—H25C	109.5
N1—C10—H10	119.5	H25A—C25—H25C	109.5
C11—C10—H10	119.5	H25B—C25—H25C	109.5
C12—C11—C16	119.4 (2)	Cl3—C26—Cl1	110.58 (17)
C12—C11—C10	120.85 (19)	Cl3—C26—Cl2	110.98 (16)
C16—C11—C10	119.7 (2)	Cl1—C26—Cl2	109.26 (16)
O1—C12—C11	121.96 (19)	Cl3—C26—H26	108.7
O1—C12—C13	117.9 (2)	Cl1—C26—H26	108.7
C11—C12—C13	120.2 (2)	Cl2—C26—H26	108.7
C6—C1—C2—C3	3.1 (3)	C17—O2—C13—C14	3.3 (4)
C7—C1—C2—C3	−177.8 (2)	C17—O2—C13—C12	−176.9 (2)
C1—C2—C3—C4	−1.0 (3)	O1—C12—C13—O2	−0.5 (3)
C1—C2—C3—C8	179.3 (2)	C11—C12—C13—O2	179.3 (2)
C2—C3—C4—C5	−3.3 (3)	O1—C12—C13—C14	179.3 (2)
C8—C3—C4—C5	176.4 (2)	C11—C12—C13—C14	−0.9 (3)
C2—C3—C4—N2	−179.66 (19)	O2—C13—C14—C15	−180.0 (2)
C8—C3—C4—N2	0.0 (3)	C12—C13—C14—C15	0.3 (4)
C18—N2—C4—C5	93.5 (3)	C13—C14—C15—C16	0.4 (4)
C18—N2—C4—C3	−90.1 (3)	C14—C15—C16—C11	−0.4 (4)
C3—C4—C5—C6	5.2 (3)	C12—C11—C16—C15	−0.2 (3)
N2—C4—C5—C6	−178.49 (19)	C10—C11—C16—C15	178.8 (2)
C3—C4—C5—C9	−175.3 (2)	C4—N2—C18—C19	174.8 (2)
N2—C4—C5—C9	1.0 (3)	N2—C18—C19—C24	−3.0 (3)
C2—C1—C6—C5	−1.0 (3)	N2—C18—C19—C20	179.1 (2)
C7—C1—C6—C5	179.9 (2)	C24—C19—C20—C21	−0.2 (4)
C2—C1—C6—N1	173.84 (19)	C18—C19—C20—C21	177.7 (3)
C7—C1—C6—N1	−5.2 (3)	C19—C20—C21—C22	−0.8 (5)
C4—C5—C6—C1	−3.0 (3)	C20—C21—C22—C23	1.2 (5)
C9—C5—C6—C1	177.5 (2)	C25—O4—C23—C22	18.3 (4)
C4—C5—C6—N1	−178.06 (18)	C25—O4—C23—C24	−162.4 (3)
C9—C5—C6—N1	2.4 (3)	C21—C22—C23—O4	178.7 (3)
C10—N1—C6—C1	58.0 (3)	C21—C22—C23—C24	−0.5 (4)
C10—N1—C6—C5	−126.9 (2)	C20—C19—C24—O3	−179.0 (2)
C6—N1—C10—C11	−177.39 (19)	C18—C19—C24—O3	3.0 (3)
N1—C10—C11—C12	1.3 (3)	C20—C19—C24—C23	0.9 (3)
N1—C10—C11—C16	−177.7 (2)	C18—C19—C24—C23	−177.1 (2)
C16—C11—C12—O1	−179.3 (2)	O4—C23—C24—O3	0.1 (3)
C10—C11—C12—O1	1.7 (3)	C22—C23—C24—O3	179.4 (2)
C16—C11—C12—C13	0.8 (3)	O4—C23—C24—C19	−179.9 (2)
C10—C11—C12—C13	−178.2 (2)	C22—C23—C24—C19	−0.6 (4)

D—H···A	D—H	H···A	D···A	D—H···A
O1—H1···N1	0.89 (3)	1.76 (4)	2.566 (3)	150 (3)
O3—H3···N2	0.87 (4)	1.83 (4)	2.618 (2)	150 (4)
C26—H26···O1i	0.98	2.16	3.071 (4)	154

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1—H1⋯N1	0.89 (3)	1.76 (4)	2.566 (3)	150 (3)
O3—H3⋯N2	0.87 (4)	1.83 (4)	2.618 (2)	150 (4)
C26—H26⋯O1i	0.98	2.16	3.071 (4)	154

Symmetry code: (i) .