| Literature DB >> 22596035 |
David R Levine1, Anthony Caruso, Maxime A Siegler, John D Tovar.
Abstract
The synthesis of new boron-containing acenes (meta-B-entacenes) is reported. These compounds exhibit slightly non-planar core geometries with blue-shifted spectral properties and more negative electrochemical reduction potentials relative to known para isomers. Polarizable π-extended architectures were realized via cross-coupling procedures with chloro-functionalized precursors.Entities:
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Year: 2012 PMID： 22596035 DOI： 10.1039/c2cc32500d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222