Literature DB >> 22595768

Rational design of a phthalocyanine-perylenediimide dyad with a long-lived charge-separated state.

Vicente M Blas-Ferrando1, Javier Ortiz, Latifa Bouissane, Kei Ohkubo, Shunichi Fukuzumi, Fernando Fernández-Lázaro, Angela Sastre-Santos.   

Abstract

A new ZnPc-PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substituents. The lifetime of the charge-separated state was 72 μs.

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Year:  2012        PMID: 22595768     DOI: 10.1039/c2cc31087b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Room temperature synthesis of perylene diimides facilitated by high amic acid solubility.

Authors:  Markus C Kwakernaak; Marijn Koel; Peter J L van den Berg; Erik M Kelder; Wolter F Jager
Journal:  Org Chem Front       Date:  2022-01-10       Impact factor: 5.281

2.  Occurrence of excited state charge separation in a N-doped graphene-perylenediimide hybrid formed via 'click' chemistry.

Authors:  Habtom B Gobeze; Luis M Arellano; Ana María Gutiérrez-Vílchez; María J Gómez-Escalonilla; Ángela Sastre-Santos; Fernando Fernández-Lázaro; Fernando Langa; Francis D'Souza
Journal:  Nanoscale Adv       Date:  2019-08-30

3.  Tunable and highly efficient light-harvesting antenna systems based on 1,7-perylene-3,4,9,10-tetracarboxylic acid derivatives.

Authors:  Rajeev K Dubey; Damla Inan; Sanchita Sengupta; Ernst J R Sudhölter; Ferdinand C Grozema; Wolter F Jager
Journal:  Chem Sci       Date:  2016-03-15       Impact factor: 9.825

  3 in total

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