| Literature DB >> 22594835 |
Koichi Mitsudo1, Shuichi Shimohara, Jun Mizoguchi, Hiroki Mandai, Seiji Suga.
Abstract
The first synthesis of nitrogen-bridged terthiophenes (NBTTs) has been achieved by a tandem Buchwald-Hartwig coupling of 3,3',3",4'-tetrabromo-2,2':5',2"-terthiophene. Several NBTT derivatives bearing aryl or alkyl moieties on the N-atoms could be synthesized. Their fundamental electrochemical characteristics and HOMO-LUMO levels were found to be influenced by the substituents on the N-atoms.Entities:
Year: 2012 PMID： 22594835 DOI： 10.1021/ol300887t
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005