| Literature DB >> 22591008 |
Claire Jahier1, Olga V Zatolochnaya, Nickolay V Zvyagintsev, Valentine P Ananikov, Vladimir Gevorgyan.
Abstract
A general highly regio- and stereoselective palladium-catalyzed head-to-head dimerization reaction of terminal acetylenes is presented. This methodology allows for the efficient synthesis of a variety of 1,4-enynes as single E stereoisomers. Computational studies reveal that this dimerization reaction proceeds via the hydropalladation pathway.Entities:
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Year: 2012 PMID： 22591008 DOI： 10.1021/ol3010936
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005