Tetra-kis(triphenyl-phosphane-κP)silver(I) tetra-fluorido-borate.

The title complex, [Ag(C(18)H(15)P)(4)]BF(4), was prepared by the reaction of silver(I) tetra-fluorido-borate and triphenyl-phosphane in the presence of 1,2-bis-(pyridin-2-yl)ethyl-ene. The Ag(I) atom is tetra-hedrally coordinated by four P atoms from triphenyl-phosphane (PPh(3)) ligands. Due to symmetry, the tetra-fluorido-borate anion is disordered over three positions (each with one third occupancy). The tetra-fluorido-borate anion does not coordinate to the Ag(I) atom.

Related literature

For background to silver(I) complexes, see: Bowmaker et al. (1993 ▶); Cui, Hu et al. (2010 ▶); Cui, Jin et al. (2010 ▶); Jin, Hu et al. (2010 ▶); Jin, Song et al. (2010 ▶); Meijboom et al. (2009 ▶). For related structures, see: Engelhardt et al. (1985 ▶); Wen et al. (2011 ▶).

Experimental

Crystal data

[Ag(C18H15P)4]BF4

M = 1243.76

Trigonal,

a = 14.2445 (12) Å

c = 51.591 (4) Å

V = 9065.7 (12) Å3

Z = 6

Mo Kα radiation

μ = 0.50 mm−1

T = 298 K

0.30 × 0.18 × 0.15 mm

Data collection

Bruker SMART 1000 CCD diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2007 ▶) T min = 0.866, T max = 0.930

15472 measured reflections

3548 independent reflections

2167 reflections with I > 2σ(I)

R int = 0.092

Refinement

R[F 2 > 2σ(F 2)] = 0.063

wR(F 2) = 0.160

S = 1.07

3548 reflections

272 parameters

1 restraint

H-atom parameters constrained

Δρmax = 1.34 e Å−3

Δρmin = −0.52 e Å−3

Data collection: SMART (Bruker, 2007 ▶); cell refinement: SAINT-Plus (Bruker, 2007 ▶); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536812018247/ez2286sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536812018247/ez2286Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ag(C18H15P)4]BF4	Dx = 1.367 Mg m−3
Mr = 1243.76	Mo Kα radiation, λ = 0.71073 Å
Trigonal, R3	Cell parameters from 2109 reflections
a = 14.2445 (12) Å	θ = 2.4–18.9°
c = 51.591 (4) Å	µ = 0.50 mm−1
V = 9065.7 (12) Å3	T = 298 K
Z = 6	White, block
F(000) = 3840	0.30 × 0.18 × 0.15 mm

Bruker SMART 1000 CCD diffractometer	3548 independent reflections
Radiation source: fine-focus sealed tube	2167 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.092
phi and ω scans	θmax = 25.0°, θmin = 2.3°
Absorption correction: multi-scan (SADABS; Bruker, 2007)	h = −16→16
Tmin = 0.866, Tmax = 0.930	k = −15→16
15472 measured reflections	l = −61→40

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.063	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.160	H-atom parameters constrained
S = 1.07	w = 1/[σ2(Fo2) + (0.0699P)2] where P = (Fo2 + 2Fc2)/3
3548 reflections	(Δ/σ)max = 0.001
272 parameters	Δρmax = 1.34 e Å−3
1 restraint	Δρmin = −0.52 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag1	0.6667	0.3333	0.081276 (13)	0.0476 (3)
P1	0.80962 (10)	0.53162 (10)	0.06400 (3)	0.0464 (4)
P2	0.6667	0.3333	0.13231 (4)	0.0475 (6)
F1	0.364 (3)	0.600 (2)	0.1780 (6)	0.112 (6)	0.33
F2	0.273 (4)	0.604 (2)	0.1863 (5)	0.166 (11)	0.33
F3	0.021 (3)	0.921 (2)	0.0089 (5)	0.140 (6)	0.33
F4	−0.023 (4)	1.036 (3)	0.0208 (3)	0.146 (9)	0.33
B1	0.3333	0.6667	0.1667	0.113 (9)
B2	0.0000	1.0000	0.0000	0.130 (10)
C1	0.9477 (4)	0.5677 (4)	0.07293 (10)	0.0490 (13)
C2	1.0219 (4)	0.6654 (4)	0.08427 (11)	0.0575 (14)
H2	1.0038	0.7192	0.0865	0.069*
C3	1.1221 (5)	0.6841 (5)	0.09236 (13)	0.0707 (17)
H3	1.1708	0.7502	0.0999	0.085*
C4	1.1502 (5)	0.6060 (5)	0.08940 (13)	0.0742 (18)
H4	1.2170	0.6179	0.0953	0.089*
C5	1.0794 (5)	0.5100 (5)	0.07767 (14)	0.0774 (19)
H5	1.0994	0.4578	0.0749	0.093*
C6	0.9783 (5)	0.4904 (5)	0.06992 (12)	0.0702 (17)
H6	0.9299	0.4239	0.0625	0.084*
C7	0.8161 (4)	0.5488 (4)	0.02889 (11)	0.0566 (15)
C8	0.9121 (5)	0.6150 (6)	0.01588 (12)	0.083 (2)
H8	0.9780	0.6462	0.0246	0.099*
C9	0.9082 (6)	0.6344 (7)	−0.01077 (15)	0.111 (3)
H9	0.9714	0.6824	−0.0195	0.133*
C10	0.8122 (7)	0.5829 (7)	−0.02380 (14)	0.097 (2)
H10	0.8104	0.5951	−0.0415	0.117*
C11	0.7195 (6)	0.5142 (6)	−0.01119 (13)	0.0782 (18)
H11	0.6550	0.4776	−0.0204	0.094*
C12	0.7192 (5)	0.4979 (5)	0.01485 (11)	0.0648 (16)
H12	0.6543	0.4528	0.0233	0.078*
C13	0.8024 (4)	0.6496 (4)	0.07541 (10)	0.0486 (13)
C14	0.8377 (4)	0.7441 (4)	0.06072 (12)	0.0626 (15)
H14	0.8596	0.7463	0.0436	0.075*
C15	0.8401 (5)	0.8340 (5)	0.07156 (14)	0.0731 (18)
H15	0.8654	0.8973	0.0619	0.088*
C16	0.8049 (5)	0.8295 (5)	0.09661 (15)	0.0754 (19)
H16	0.8075	0.8905	0.1039	0.090*
C17	0.7665 (5)	0.7372 (5)	0.11083 (12)	0.0705 (17)
H17	0.7405	0.7345	0.1275	0.085*
C18	0.7660 (4)	0.6478 (5)	0.10054 (11)	0.0612 (15)
H18	0.7410	0.5854	0.1105	0.073*
C19	0.6357 (4)	0.4300 (4)	0.14761 (10)	0.0493 (13)
C20	0.6937 (5)	0.4944 (5)	0.16853 (11)	0.0652 (16)
H20	0.7538	0.4923	0.1749	0.078*
C21	0.6615 (6)	0.5616 (5)	0.17986 (13)	0.085 (2)
H21	0.6982	0.6021	0.1944	0.101*
C22	0.5770 (6)	0.5693 (5)	0.17011 (14)	0.0799 (19)
H22	0.5571	0.6161	0.1777	0.096*
C23	0.5210 (5)	0.5077 (5)	0.14904 (13)	0.0760 (18)
H23	0.4633	0.5131	0.1423	0.091*
C24	0.5495 (5)	0.4394 (5)	0.13809 (12)	0.0641 (16)
H24	0.5106	0.3978	0.1239	0.077*

	U11	U22	U33	U12	U13	U23
Ag1	0.0492 (3)	0.0492 (3)	0.0444 (5)	0.02459 (16)	0.000	0.000
P1	0.0451 (8)	0.0450 (7)	0.0468 (9)	0.0208 (6)	0.0015 (6)	0.0032 (6)
P2	0.0519 (9)	0.0519 (9)	0.0387 (13)	0.0260 (4)	0.000	0.000
F1	0.124 (15)	0.082 (12)	0.163 (18)	0.076 (10)	−0.001 (18)	0.001 (14)
F2	0.16 (3)	0.12 (2)	0.17 (2)	0.038 (15)	0.014 (19)	0.048 (16)
F3	0.158 (18)	0.134 (19)	0.14 (2)	0.081 (14)	0.01 (2)	0.020 (17)
F4	0.17 (3)	0.15 (3)	0.098 (12)	0.066 (18)	0.02 (2)	−0.027 (17)
B1	0.094 (15)	0.094 (15)	0.15 (3)	0.047 (7)	0.000	0.000
B2	0.14 (2)	0.14 (2)	0.10 (4)	0.071 (12)	0.000	0.000
C1	0.048 (3)	0.045 (3)	0.054 (3)	0.024 (3)	0.005 (3)	0.006 (3)
C2	0.043 (3)	0.054 (3)	0.074 (4)	0.022 (3)	−0.003 (3)	−0.005 (3)
C3	0.053 (4)	0.060 (4)	0.087 (5)	0.019 (3)	−0.011 (3)	−0.011 (3)
C4	0.041 (3)	0.085 (5)	0.095 (5)	0.030 (4)	−0.003 (3)	0.008 (4)
C5	0.060 (4)	0.071 (4)	0.111 (6)	0.040 (4)	−0.001 (4)	−0.001 (4)
C6	0.058 (4)	0.062 (4)	0.088 (5)	0.028 (3)	−0.004 (3)	−0.004 (3)
C7	0.059 (4)	0.059 (4)	0.052 (3)	0.030 (3)	0.002 (3)	0.006 (3)
C8	0.062 (4)	0.109 (5)	0.061 (4)	0.030 (4)	0.005 (3)	0.019 (4)
C9	0.092 (6)	0.147 (8)	0.071 (5)	0.043 (5)	0.027 (5)	0.035 (5)
C10	0.105 (6)	0.138 (7)	0.054 (4)	0.065 (6)	−0.003 (5)	0.015 (5)
C11	0.087 (5)	0.096 (5)	0.061 (4)	0.054 (4)	−0.013 (4)	−0.004 (4)
C12	0.071 (4)	0.070 (4)	0.054 (4)	0.036 (3)	−0.005 (3)	−0.001 (3)
C13	0.044 (3)	0.044 (3)	0.054 (3)	0.019 (3)	0.000 (3)	0.004 (3)
C14	0.065 (4)	0.059 (4)	0.063 (4)	0.031 (3)	0.003 (3)	0.006 (3)
C15	0.084 (5)	0.052 (4)	0.092 (5)	0.040 (4)	−0.010 (4)	0.007 (4)
C16	0.074 (4)	0.058 (4)	0.100 (6)	0.037 (4)	−0.009 (4)	−0.012 (4)
C17	0.069 (4)	0.078 (5)	0.072 (4)	0.042 (4)	−0.002 (3)	−0.014 (4)
C18	0.061 (4)	0.053 (3)	0.066 (4)	0.025 (3)	0.007 (3)	0.005 (3)
C19	0.057 (3)	0.057 (3)	0.039 (3)	0.032 (3)	0.000 (3)	0.003 (3)
C20	0.079 (4)	0.074 (4)	0.061 (4)	0.051 (4)	−0.015 (3)	−0.023 (3)
C21	0.095 (5)	0.087 (5)	0.074 (5)	0.047 (4)	−0.015 (4)	−0.026 (4)
C22	0.092 (5)	0.075 (4)	0.088 (5)	0.053 (4)	0.011 (4)	−0.008 (4)
C23	0.076 (4)	0.081 (4)	0.082 (5)	0.048 (4)	0.001 (4)	0.001 (4)
C24	0.070 (4)	0.075 (4)	0.054 (4)	0.042 (3)	−0.002 (3)	−0.004 (3)

Ag1—P2	2.633 (2)	B2—F3viii	1.38 (2)
Ag1—P1i	2.6772 (13)	B2—F3ix	1.38 (2)
Ag1—P1	2.6772 (13)	B2—F3x	1.38 (2)
Ag1—P1ii	2.6772 (13)	B2—F3xi	1.38 (2)
P1—C7	1.824 (6)	C1—C6	1.380 (7)
P1—C1	1.826 (5)	C1—C2	1.388 (7)
P1—C13	1.831 (5)	C2—C3	1.379 (7)
P2—C19i	1.822 (5)	C2—H2	0.9300
P2—C19ii	1.822 (5)	C3—C4	1.367 (8)
P2—C19	1.822 (5)	C3—H3	0.9300
F1—F2iii	0.97 (4)	C4—C5	1.369 (8)
F1—B1	1.37 (2)	C4—H4	0.9300
F1—F2	1.39 (5)	C5—C6	1.382 (8)
F1—F2iv	1.66 (2)	C5—H5	0.9300
F1—F1iv	1.70 (4)	C6—H6	0.9300
F1—F1v	1.70 (4)	C7—C8	1.386 (8)
F2—F1vi	0.97 (4)	C7—C12	1.398 (8)
F2—B1	1.34 (3)	C8—C9	1.409 (9)
F2—F2iii	1.52 (4)	C8—H8	0.9300
F2—F2vi	1.52 (4)	C9—C10	1.363 (10)
F2—F1v	1.66 (2)	C9—H9	0.9300
F3—F4vii	1.16 (4)	C10—C11	1.353 (9)
F3—B2	1.38 (2)	C10—H10	0.9300
F3—F4viii	1.42 (5)	C11—C12	1.363 (8)
F3—F3ix	1.59 (3)	C11—H11	0.9300
F3—F3x	1.59 (3)	C12—H12	0.9300
F3—F4xi	1.65 (3)	C13—C18	1.392 (7)
F4—F3viii	1.16 (4)	C13—C14	1.401 (7)
F4—F4vii	1.27 (4)	C14—C15	1.382 (8)
F4—F4viii	1.27 (4)	C14—H14	0.9300
F4—B2	1.301 (18)	C15—C16	1.376 (9)
F4—F3vii	1.42 (5)	C15—H15	0.9300
F4—F3xi	1.65 (3)	C16—C17	1.359 (8)
B1—F2iv	1.34 (3)	C16—H16	0.9300
B1—F2xii	1.34 (3)	C17—C18	1.377 (8)
B1—F2v	1.34 (3)	C17—H17	0.9300
B1—F2vi	1.34 (3)	C18—H18	0.9300
B1—F2iii	1.34 (3)	C19—C24	1.389 (7)
B1—F1iv	1.37 (2)	C19—C20	1.390 (7)
B1—F1v	1.37 (2)	C20—C21	1.381 (8)
B1—F1vi	1.37 (2)	C20—H20	0.9300
B1—F1iii	1.37 (2)	C21—C22	1.360 (9)
B1—F1xii	1.37 (2)	C21—H21	0.9300
B2—F4viii	1.301 (18)	C22—C23	1.374 (9)
B2—F4vii	1.301 (18)	C22—H22	0.9300
B2—F4xi	1.301 (18)	C23—C24	1.352 (8)
B2—F4x	1.301 (18)	C23—H23	0.9300
B2—F4ix	1.301 (18)	C24—H24	0.9300
B2—F3vii	1.38 (2)
P2—Ag1—P1i	109.45 (3)	F1vi—B1—F1xii	76.9 (13)
P2—Ag1—P1	109.45 (3)	F1iii—B1—F1xii	76.9 (13)
P1i—Ag1—P1	109.49 (3)	F1—B1—F1xii	179.994 (18)
P2—Ag1—P1ii	109.45 (3)	F4viii—B2—F4vii	58.5 (15)
P1i—Ag1—P1ii	109.49 (3)	F4viii—B2—F4	58.5 (15)
P1—Ag1—P1ii	109.49 (3)	F4vii—B2—F4	58.5 (15)
C7—P1—C1	103.8 (2)	F4viii—B2—F4xi	121.5 (15)
C7—P1—C13	102.6 (2)	F4vii—B2—F4xi	121.5 (15)
C1—P1—C13	102.0 (2)	F4—B2—F4xi	180.0 (8)
C7—P1—Ag1	115.64 (18)	F4viii—B2—F4x	121.5 (15)
C1—P1—Ag1	110.91 (16)	F4vii—B2—F4x	180 (2)
C13—P1—Ag1	119.93 (17)	F4—B2—F4x	121.5 (15)
C19i—P2—C19ii	102.6 (2)	F4xi—B2—F4x	58.5 (15)
C19i—P2—C19	102.6 (2)	F4viii—B2—F4ix	180.0 (8)
C19ii—P2—C19	102.6 (2)	F4vii—B2—F4ix	121.5 (15)
C19i—P2—Ag1	115.66 (17)	F4—B2—F4ix	121.5 (15)
C19ii—P2—Ag1	115.66 (17)	F4xi—B2—F4ix	58.5 (15)
C19—P2—Ag1	115.66 (17)	F4x—B2—F4ix	58.5 (15)
F2iii—F1—B1	67 (3)	F4viii—B2—F3vii	51 (2)
F2iii—F1—F2	78 (3)	F4vii—B2—F3vii	104.3 (14)
B1—F1—F2	58.1 (14)	F4—B2—F3vii	64 (2)
F2iii—F1—F2iv	111 (4)	F4xi—B2—F3vii	116 (2)
B1—F1—F2iv	51.4 (15)	F4x—B2—F3vii	75.7 (14)
F2—F1—F2iv	92 (2)	F4ix—B2—F3vii	129 (2)
F2iii—F1—F1iv	71 (2)	F4viii—B2—F3viii	104.3 (14)
B1—F1—F1iv	51.5 (7)	F4vii—B2—F3viii	64 (2)
F2—F1—F1iv	109.3 (15)	F4—B2—F3viii	51 (2)
F2iv—F1—F1iv	49 (2)	F4xi—B2—F3viii	129 (2)
F2iii—F1—F1v	118 (3)	F4x—B2—F3viii	116 (2)
B1—F1—F1v	51.5 (7)	F4ix—B2—F3viii	75.7 (14)
F2—F1—F1v	64.0 (10)	F3vii—B2—F3viii	109.5 (10)
F2iv—F1—F1v	33.5 (15)	F4viii—B2—F3ix	75.7 (14)
F1iv—F1—F1v	78 (2)	F4vii—B2—F3ix	116 (2)
F1vi—F2—B1	71 (3)	F4—B2—F3ix	129 (2)
F1vi—F2—F1	130 (5)	F4xi—B2—F3ix	51 (2)
B1—F2—F1	60 (2)	F4x—B2—F3ix	64 (2)
F1vi—F2—F2iii	117 (3)	F4ix—B2—F3ix	104.3 (14)
B1—F2—F2iii	55.4 (9)	F3vii—B2—F3ix	70.5 (10)
F1—F2—F2iii	39 (2)	F3viii—B2—F3ix	180 (2)
F1vi—F2—F2vi	63 (3)	F4viii—B2—F3x	129 (2)
B1—F2—F2vi	55.4 (9)	F4vii—B2—F3x	75.7 (14)
F1—F2—F2vi	95 (2)	F4—B2—F3x	116 (2)
F2iii—F2—F2vi	60.000 (9)	F4xi—B2—F3x	64 (2)
F1vi—F2—F1v	76 (3)	F4x—B2—F3x	104.3 (14)
B1—F2—F1v	53.0 (11)	F4ix—B2—F3x	51 (2)
F1—F2—F1v	67 (3)	F3vii—B2—F3x	180 (2)
F2iii—F2—F1v	93.8 (19)	F3viii—B2—F3x	70.5 (10)
F2vi—F2—F1v	105.2 (11)	F3ix—B2—F3x	109.5 (10)
F4vii—F3—B2	61.0 (17)	F4viii—B2—F3	64 (2)
F4vii—F3—F4viii	58 (2)	F4vii—B2—F3	51 (2)
B2—F3—F4viii	55.5 (14)	F4—B2—F3	104.3 (14)
F4vii—F3—F3ix	110.8 (16)	F4xi—B2—F3	75.7 (14)
B2—F3—F3ix	54.7 (5)	F4x—B2—F3	129 (2)
F4viii—F3—F3ix	66.1 (12)	F4ix—B2—F3	116 (2)
F4vii—F3—F3x	71.6 (15)	F3vii—B2—F3	109.5 (10)
B2—F3—F3x	54.7 (5)	F3viii—B2—F3	109.5 (10)
F4viii—F3—F3x	106.9 (14)	F3ix—B2—F3	70.5 (10)
F3ix—F3—F3x	90 (2)	F3x—B2—F3	70.5 (10)
F4vii—F3—F4xi	107 (3)	F4viii—B2—F3xi	116 (2)
B2—F3—F4xi	50.0 (13)	F4vii—B2—F3xi	129 (2)
F4viii—F3—F4xi	95 (3)	F4—B2—F3xi	75.7 (14)
F3ix—F3—F4xi	41.9 (19)	F4xi—B2—F3xi	104.3 (14)
F3x—F3—F4xi	52 (2)	F4x—B2—F3xi	51 (2)
F3viii—F4—F4vii	71 (4)	F4ix—B2—F3xi	64 (2)
F3viii—F4—F4viii	121 (3)	F3vii—B2—F3xi	70.5 (10)
F4vii—F4—F4viii	60.000 (6)	F3viii—B2—F3xi	70.5 (10)
F3viii—F4—B2	67.9 (19)	F3ix—B2—F3xi	109.5 (10)
F4vii—F4—B2	60.7 (7)	F3x—B2—F3xi	109.5 (10)
F4viii—F4—B2	60.7 (7)	F3—B2—F3xi	180 (2)
F3viii—F4—F3vii	122 (3)	C6—C1—C2	117.4 (5)
F4vii—F4—F3vii	104 (3)	C6—C1—P1	118.2 (4)
F4viii—F4—F3vii	51 (3)	C2—C1—P1	124.2 (4)
B2—F4—F3vii	60.8 (19)	C3—C2—C1	121.2 (5)
F3viii—F4—F3xi	66.5 (14)	C3—C2—H2	119.4
F4vii—F4—F3xi	111.3 (13)	C1—C2—H2	119.4
F4viii—F4—F3xi	102 (2)	C4—C3—C2	120.3 (6)
B2—F4—F3xi	54.3 (9)	C4—C3—H3	119.8
F3vii—F4—F3xi	62.1 (16)	C2—C3—H3	119.8
F2iv—B1—F2xii	69.2 (18)	C3—C4—C5	119.5 (6)
F2iv—B1—F2v	69.2 (18)	C3—C4—H4	120.2
F2xii—B1—F2v	69.2 (18)	C5—C4—H4	120.2
F2iv—B1—F2vi	180.0 (15)	C4—C5—C6	120.2 (6)
F2xii—B1—F2vi	110.8 (18)	C4—C5—H5	119.9
F2v—B1—F2vi	110.8 (18)	C6—C5—H5	119.9
F2iv—B1—F2	110.8 (18)	C1—C6—C5	121.3 (6)
F2xii—B1—F2	179.995 (13)	C1—C6—H6	119.3
F2v—B1—F2	110.8 (18)	C5—C6—H6	119.3
F2vi—B1—F2	69.2 (18)	C8—C7—C12	118.9 (5)
F2iv—B1—F2iii	110.8 (18)	C8—C7—P1	122.6 (5)
F2xii—B1—F2iii	110.8 (18)	C12—C7—P1	118.3 (4)
F2v—B1—F2iii	179.994 (19)	C7—C8—C9	119.0 (6)
F2vi—B1—F2iii	69.2 (18)	C7—C8—H8	120.5
F2—B1—F2iii	69.2 (18)	C9—C8—H8	120.5
F2iv—B1—F1iv	62 (2)	C10—C9—C8	120.2 (7)
F2xii—B1—F1iv	42.0 (17)	C10—C9—H9	119.9
F2v—B1—F1iv	104.4 (11)	C8—C9—H9	119.9
F2vi—B1—F1iv	118 (2)	C11—C10—C9	120.3 (7)
F2—B1—F1iv	138.0 (17)	C11—C10—H10	119.8
F2iii—B1—F1iv	75.6 (11)	C9—C10—H10	119.8
F2iv—B1—F1v	42.0 (18)	C10—C11—C12	121.1 (7)
F2xii—B1—F1v	104.4 (11)	C10—C11—H11	119.5
F2v—B1—F1v	62 (2)	C12—C11—H11	119.5
F2vi—B1—F1v	138.0 (17)	C11—C12—C7	120.3 (6)
F2—B1—F1v	75.6 (11)	C11—C12—H12	119.9
F2iii—B1—F1v	118 (2)	C7—C12—H12	119.9
F1iv—B1—F1v	103.1 (13)	C18—C13—C14	118.2 (5)
F2iv—B1—F1vi	118 (2)	C18—C13—P1	118.3 (4)
F2xii—B1—F1vi	138.0 (17)	C14—C13—P1	123.4 (4)
F2v—B1—F1vi	75.6 (11)	C15—C14—C13	120.1 (6)
F2vi—B1—F1vi	62 (2)	C15—C14—H14	119.9
F2—B1—F1vi	42.0 (17)	C13—C14—H14	119.9
F2iii—B1—F1vi	104.4 (11)	C16—C15—C14	119.8 (6)
F1iv—B1—F1vi	179.996 (10)	C16—C15—H15	120.1
F1v—B1—F1vi	76.9 (13)	C14—C15—H15	120.1
F2iv—B1—F1iii	138.0 (17)	C17—C16—C15	120.8 (6)
F2xii—B1—F1iii	75.6 (11)	C17—C16—H16	119.6
F2v—B1—F1iii	118 (2)	C15—C16—H16	119.6
F2vi—B1—F1iii	42.0 (18)	C16—C17—C18	120.0 (6)
F2—B1—F1iii	104.4 (11)	C16—C17—H17	120.0
F2iii—B1—F1iii	62 (2)	C18—C17—H17	120.0
F1iv—B1—F1iii	76.9 (13)	C17—C18—C13	120.8 (6)
F1v—B1—F1iii	180.0 (11)	C17—C18—H18	119.6
F1vi—B1—F1iii	103.1 (13)	C13—C18—H18	119.6
F2iv—B1—F1	75.6 (11)	C24—C19—C20	118.3 (5)
F2xii—B1—F1	118 (2)	C24—C19—P2	118.6 (4)
F2v—B1—F1	138.1 (17)	C20—C19—P2	123.1 (4)
F2vi—B1—F1	104.4 (11)	C21—C20—C19	119.5 (6)
F2—B1—F1	62 (2)	C21—C20—H20	120.3
F2iii—B1—F1	42.0 (17)	C19—C20—H20	120.3
F1iv—B1—F1	76.9 (13)	C22—C21—C20	120.9 (6)
F1v—B1—F1	76.9 (13)	C22—C21—H21	119.5
F1vi—B1—F1	103.1 (13)	C20—C21—H21	119.5
F1iii—B1—F1	103.1 (13)	C21—C22—C23	119.8 (6)
F2iv—B1—F1xii	104.4 (11)	C21—C22—H22	120.1
F2xii—B1—F1xii	62 (2)	C23—C22—H22	120.1
F2v—B1—F1xii	42.0 (17)	C24—C23—C22	120.2 (6)
F2vi—B1—F1xii	75.6 (11)	C24—C23—H23	119.9
F2—B1—F1xii	118 (2)	C22—C23—H23	119.9
F2iii—B1—F1xii	138.0 (17)	C23—C24—C19	121.3 (6)
F1iv—B1—F1xii	103.1 (13)	C23—C24—H24	119.3
F1v—B1—F1xii	103.1 (13)	C19—C24—H24	119.3
P2—Ag1—P1—C7	−177.16 (19)	F3viii—F4—B2—F4xi	65 (100)
P1i—Ag1—P1—C7	62.9 (2)	F4vii—F4—B2—F4xi	145 (100)
P1ii—Ag1—P1—C7	−57.2 (2)	F4viii—F4—B2—F4xi	−145 (100)
P2—Ag1—P1—C1	65.07 (18)	F3vii—F4—B2—F4xi	−86 (100)
P1i—Ag1—P1—C1	−54.9 (2)	F3xi—F4—B2—F4xi	−11 (100)
P1ii—Ag1—P1—C1	−174.96 (18)	F3viii—F4—B2—F4x	100 (4)
P2—Ag1—P1—C13	−53.4 (2)	F4vii—F4—B2—F4x	180.000 (11)
P1i—Ag1—P1—C13	−173.35 (19)	F4viii—F4—B2—F4x	−110.1 (6)
P1ii—Ag1—P1—C13	66.6 (2)	F3vii—F4—B2—F4x	−51 (3)
P1i—Ag1—P2—C19i	57.77 (18)	F3xi—F4—B2—F4x	24 (4)
P1—Ag1—P2—C19i	−62.23 (18)	F3viii—F4—B2—F4ix	30 (4)
P1ii—Ag1—P2—C19i	177.77 (18)	F4vii—F4—B2—F4ix	110.1 (6)
P1i—Ag1—P2—C19ii	−62.23 (18)	F4viii—F4—B2—F4ix	180.000 (14)
P1—Ag1—P2—C19ii	177.77 (18)	F3vii—F4—B2—F4ix	−121 (3)
P1ii—Ag1—P2—C19ii	57.77 (18)	F3xi—F4—B2—F4ix	−46 (4)
P1i—Ag1—P2—C19	177.77 (18)	F3viii—F4—B2—F3vii	151.3 (19)
P1—Ag1—P2—C19	57.77 (18)	F4vii—F4—B2—F3vii	−129 (3)
P1ii—Ag1—P2—C19	−62.23 (18)	F4viii—F4—B2—F3vii	−59 (3)
F2iii—F1—F2—F1vi	84 (6)	F3xi—F4—B2—F3vii	75.0 (10)
B1—F1—F2—F1vi	13 (4)	F4vii—F4—B2—F3viii	80 (4)
F2iv—F1—F2—F1vi	−27 (4)	F4viii—F4—B2—F3viii	150 (4)
F1iv—F1—F2—F1vi	20 (6)	F3vii—F4—B2—F3viii	−151.3 (19)
F1v—F1—F2—F1vi	−46 (3)	F3xi—F4—B2—F3viii	−76.3 (9)
F2iii—F1—F2—B1	71 (3)	F3viii—F4—B2—F3ix	180.000 (2)
F2iv—F1—F2—B1	−40.6 (18)	F4vii—F4—B2—F3ix	−100 (4)
F1iv—F1—F2—B1	6 (2)	F4viii—F4—B2—F3ix	−30 (4)
F1v—F1—F2—B1	−59.2 (9)	F3vii—F4—B2—F3ix	28.7 (19)
B1—F1—F2—F2iii	−71 (3)	F3xi—F4—B2—F3ix	103.7 (9)
F2iv—F1—F2—F2iii	−111 (4)	F3viii—F4—B2—F3x	−28.7 (19)
F1iv—F1—F2—F2iii	−65 (2)	F4vii—F4—B2—F3x	51 (3)
F1v—F1—F2—F2iii	−130 (4)	F4viii—F4—B2—F3x	121 (3)
F2iii—F1—F2—F2vi	25 (3)	F3vii—F4—B2—F3x	180.000 (8)
B1—F1—F2—F2vi	−45.4 (10)	F3xi—F4—B2—F3x	−105.0 (10)
F2iv—F1—F2—F2vi	−86 (2)	F3viii—F4—B2—F3	−103.7 (9)
F1iv—F1—F2—F2vi	−39 (2)	F4vii—F4—B2—F3	−24 (4)
F1v—F1—F2—F2vi	−104.6 (15)	F4viii—F4—B2—F3	46 (4)
F2iii—F1—F2—F1v	130 (4)	F3vii—F4—B2—F3	105.0 (10)
B1—F1—F2—F1v	59.2 (9)	F3xi—F4—B2—F3	180.00 (2)
F2iv—F1—F2—F1v	18.6 (17)	F3viii—F4—B2—F3xi	76.3 (9)
F1iv—F1—F2—F1v	65 (3)	F4vii—F4—B2—F3xi	156 (4)
F1vi—F2—B1—F2iv	−110 (4)	F4viii—F4—B2—F3xi	−134 (4)
F1—F2—B1—F2iv	59.5 (19)	F3vii—F4—B2—F3xi	−75.0 (10)
F2iii—F2—B1—F2iv	105.2 (9)	F4vii—F3—B2—F4viii	70 (2)
F2vi—F2—B1—F2iv	180.000 (12)	F3ix—F3—B2—F4viii	−83.3 (15)
F1v—F2—B1—F2iv	−23 (3)	F3x—F3—B2—F4viii	156.6 (18)
F1vi—F2—B1—F2xii	72 (6)	F4xi—F3—B2—F4viii	−137 (3)
F1—F2—B1—F2xii	−119 (6)	F4viii—F3—B2—F4vii	−70 (2)
F2iii—F2—B1—F2xii	−74 (8)	F3ix—F3—B2—F4vii	−153 (2)
F2vi—F2—B1—F2xii	1 (8)	F3x—F3—B2—F4vii	87.1 (16)
F1v—F2—B1—F2xii	158 (5)	F4xi—F3—B2—F4vii	154 (3)
F1vi—F2—B1—F2v	−35 (4)	F4vii—F3—B2—F4	26 (3)
F1—F2—B1—F2v	134 (2)	F4viii—F3—B2—F4	−43 (3)
F2iii—F2—B1—F2v	180.005 (4)	F3ix—F3—B2—F4	−127 (2)
F2vi—F2—B1—F2v	−105.2 (9)	F3x—F3—B2—F4	113 (3)
F1v—F2—B1—F2v	52 (3)	F4xi—F3—B2—F4	180.00 (2)
F1vi—F2—B1—F2vi	70 (4)	F4vii—F3—B2—F4xi	−154 (3)
F1—F2—B1—F2vi	−120.5 (19)	F4viii—F3—B2—F4xi	137 (3)
F2iii—F2—B1—F2vi	−74.8 (9)	F3ix—F3—B2—F4xi	53 (2)
F1v—F2—B1—F2vi	157 (3)	F3x—F3—B2—F4xi	−67 (3)
F1vi—F2—B1—F2iii	145 (4)	F4vii—F3—B2—F4x	180.000 (15)
F1—F2—B1—F2iii	−46 (2)	F4viii—F3—B2—F4x	110 (2)
F2vi—F2—B1—F2iii	74.8 (9)	F3ix—F3—B2—F4x	27 (2)
F1v—F2—B1—F2iii	−128 (3)	F3x—F3—B2—F4x	−92.9 (16)
F1vi—F2—B1—F1iv	179.994 (11)	F4xi—F3—B2—F4x	−26 (3)
F1—F2—B1—F1iv	−11 (3)	F4vii—F3—B2—F4ix	−110 (2)
F2iii—F2—B1—F1iv	35 (4)	F4viii—F3—B2—F4ix	180.000 (12)
F2vi—F2—B1—F1iv	110 (4)	F3ix—F3—B2—F4ix	96.7 (15)
F1v—F2—B1—F1iv	−93.6 (19)	F3x—F3—B2—F4ix	−23.4 (18)
F1vi—F2—B1—F1v	−86.4 (19)	F4xi—F3—B2—F4ix	43 (3)
F1—F2—B1—F1v	82.7 (17)	F4vii—F3—B2—F3vii	92.9 (16)
F2iii—F2—B1—F1v	128 (3)	F4viii—F3—B2—F3vii	23.4 (18)
F2vi—F2—B1—F1v	−157 (3)	F3ix—F3—B2—F3vii	−60 (3)
F1—F2—B1—F1vi	169 (3)	F3x—F3—B2—F3vii	180.000 (2)
F2iii—F2—B1—F1vi	−145 (4)	F4xi—F3—B2—F3vii	−113 (3)
F2vi—F2—B1—F1vi	−70 (4)	F4vii—F3—B2—F3viii	−27 (2)
F1v—F2—B1—F1vi	86.4 (19)	F4viii—F3—B2—F3viii	−96.7 (15)
F1vi—F2—B1—F1iii	93.6 (19)	F3ix—F3—B2—F3viii	180.000 (9)
F1—F2—B1—F1iii	−97.3 (17)	F3x—F3—B2—F3viii	60 (3)
F2iii—F2—B1—F1iii	−52 (3)	F4xi—F3—B2—F3viii	127 (2)
F2vi—F2—B1—F1iii	23 (3)	F4vii—F3—B2—F3ix	153 (2)
F1v—F2—B1—F1iii	179.998 (10)	F4viii—F3—B2—F3ix	83.3 (15)
F1vi—F2—B1—F1	−169 (3)	F3x—F3—B2—F3ix	−120 (3)
F2iii—F2—B1—F1	46 (2)	F4xi—F3—B2—F3ix	−53 (2)
F2vi—F2—B1—F1	120.5 (19)	F4vii—F3—B2—F3x	−87.1 (16)
F1v—F2—B1—F1	−82.7 (17)	F4viii—F3—B2—F3x	−156.6 (18)
F1vi—F2—B1—F1xii	11 (3)	F3ix—F3—B2—F3x	120 (3)
F1—F2—B1—F1xii	180.00 (2)	F4xi—F3—B2—F3x	67 (3)
F2iii—F2—B1—F1xii	−134 (2)	F4vii—F3—B2—F3xi	−131 (3)
F2vi—F2—B1—F1xii	−59.5 (19)	F4viii—F3—B2—F3xi	159 (4)
F1v—F2—B1—F1xii	97.3 (17)	F3ix—F3—B2—F3xi	76 (4)
F2iii—F1—B1—F2iv	147 (4)	F3x—F3—B2—F3xi	−44 (4)
F2—F1—B1—F2iv	−124 (2)	F4xi—F3—B2—F3xi	22 (4)
F1iv—F1—B1—F2iv	64 (3)	C7—P1—C1—C6	−81.1 (5)
F1v—F1—B1—F2iv	−43.2 (18)	C13—P1—C1—C6	172.5 (5)
F2iii—F1—B1—F2xii	90 (4)	Ag1—P1—C1—C6	43.7 (5)
F2—F1—B1—F2xii	180.00 (2)	C7—P1—C1—C2	103.6 (5)
F2iv—F1—B1—F2xii	−56 (2)	C13—P1—C1—C2	−2.8 (5)
F1iv—F1—B1—F2xii	7 (2)	Ag1—P1—C1—C2	−131.6 (4)
F1v—F1—B1—F2xii	−99.5 (11)	C6—C1—C2—C3	−0.4 (8)
F2iii—F1—B1—F2v	−179.993 (15)	P1—C1—C2—C3	174.9 (5)
F2—F1—B1—F2v	−90 (4)	C1—C2—C3—C4	−0.2 (9)
F2iv—F1—B1—F2v	33 (4)	C2—C3—C4—C5	1.8 (10)
F1iv—F1—B1—F2v	97.2 (17)	C3—C4—C5—C6	−2.8 (10)
F1v—F1—B1—F2v	−10 (3)	C2—C1—C6—C5	−0.6 (9)
F2iii—F1—B1—F2vi	−33 (4)	P1—C1—C6—C5	−176.3 (5)
F2—F1—B1—F2vi	56 (2)	C4—C5—C6—C1	2.3 (10)
F2iv—F1—B1—F2vi	180.00 (5)	C1—P1—C7—C8	−22.7 (6)
F1iv—F1—B1—F2vi	−116 (3)	C13—P1—C7—C8	83.2 (6)
F1v—F1—B1—F2vi	136.8 (19)	Ag1—P1—C7—C8	−144.4 (5)
F2iii—F1—B1—F2	−90 (4)	C1—P1—C7—C12	161.1 (4)
F2iv—F1—B1—F2	124 (2)	C13—P1—C7—C12	−93.0 (5)
F1iv—F1—B1—F2	−173 (2)	Ag1—P1—C7—C12	39.5 (5)
F1v—F1—B1—F2	80.5 (11)	C12—C7—C8—C9	3.9 (10)
F2—F1—B1—F2iii	90 (4)	P1—C7—C8—C9	−172.2 (6)
F2iv—F1—B1—F2iii	−147 (4)	C7—C8—C9—C10	−4.2 (12)
F1iv—F1—B1—F2iii	−82.9 (17)	C8—C9—C10—C11	1.1 (13)
F1v—F1—B1—F2iii	170 (3)	C9—C10—C11—C12	2.4 (12)
F2iii—F1—B1—F1iv	82.9 (17)	C10—C11—C12—C7	−2.7 (10)
F2—F1—B1—F1iv	173 (2)	C8—C7—C12—C11	−0.5 (9)
F2iv—F1—B1—F1iv	−64 (3)	P1—C7—C12—C11	175.7 (5)
F1v—F1—B1—F1iv	−107 (2)	C7—P1—C13—C18	162.0 (4)
F2iii—F1—B1—F1v	−170 (3)	C1—P1—C13—C18	−90.7 (5)
F2—F1—B1—F1v	−80.5 (11)	Ag1—P1—C13—C18	32.2 (5)
F2iv—F1—B1—F1v	43.2 (18)	C7—P1—C13—C14	−22.0 (5)
F1iv—F1—B1—F1v	107 (2)	C1—P1—C13—C14	85.3 (5)
F2iii—F1—B1—F1vi	−97.1 (17)	Ag1—P1—C13—C14	−151.8 (4)
F2—F1—B1—F1vi	−7 (2)	C18—C13—C14—C15	2.6 (8)
F2iv—F1—B1—F1vi	116 (3)	P1—C13—C14—C15	−173.4 (4)
F1iv—F1—B1—F1vi	180.00 (2)	C13—C14—C15—C16	−1.7 (9)
F1v—F1—B1—F1vi	73 (2)	C14—C15—C16—C17	−0.8 (10)
F2iii—F1—B1—F1iii	10 (3)	C15—C16—C17—C18	2.3 (9)
F2—F1—B1—F1iii	99.5 (11)	C16—C17—C18—C13	−1.4 (9)
F2iv—F1—B1—F1iii	−136.8 (18)	C14—C13—C18—C17	−1.1 (8)
F1iv—F1—B1—F1iii	−73 (2)	P1—C13—C18—C17	175.1 (4)
F1v—F1—B1—F1iii	179.995 (15)	C19i—P2—C19—C24	171.7 (4)
F2iii—F1—B1—F1xii	−50 (5)	C19ii—P2—C19—C24	−82.0 (6)
F2—F1—B1—F1xii	40 (4)	Ag1—P2—C19—C24	44.9 (5)
F2iv—F1—B1—F1xii	164 (3)	C19i—P2—C19—C20	−8.8 (5)
F1iv—F1—B1—F1xii	−133 (4)	C19ii—P2—C19—C20	97.5 (4)
F1v—F1—B1—F1xii	120 (4)	Ag1—P2—C19—C20	−135.7 (4)
F3viii—F4—B2—F4viii	−150 (4)	C24—C19—C20—C21	2.8 (9)
F4vii—F4—B2—F4viii	−69.9 (6)	P2—C19—C20—C21	−176.7 (5)
F3vii—F4—B2—F4viii	59 (3)	C19—C20—C21—C22	−3.0 (10)
F3xi—F4—B2—F4viii	134 (4)	C20—C21—C22—C23	1.5 (11)
F3viii—F4—B2—F4vii	−80 (4)	C21—C22—C23—C24	0.3 (10)
F4viii—F4—B2—F4vii	69.9 (6)	C22—C23—C24—C19	−0.4 (10)
F3vii—F4—B2—F4vii	129 (3)	C20—C19—C24—C23	−1.1 (9)
F3xi—F4—B2—F4vii	−156 (4)	P2—C19—C24—C23	178.4 (5)