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Literature DB >> 22576375

Absolute chirality of the γ-polymorph of glycine: correlation of the absolute structure with the optical rotation.

Kazuhiko Ishikawa¹, Masahito Tanaka, Toshiya Suzuki, Akiko Sekine, Tsuneomi Kawasaki, Kenso Soai, Motoo Shiro, Meir Lahav, Toru Asahi.

Abstract

Crystal specimens of the γ-polymorph of achiral glycine which crystallize in space groups P31 and P32 as determined by the anomalous X-ray scattering method are shown to be laevorotatory and dextrorotatory, respectively, as determined by optical rotation of the crystals.

Entities: Chemical Disease Gene

Mesh：

Substances：
Glycine

Year: 2012 PMID： 22576375 DOI： 10.1039/c2cc30549f

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

1 in total

1. Determination of the Faraday rotation perpendicular to the optical axis in uniaxial CeF₃ crystal by using the Generalized-High Accuracy Universal Polarimeter.

Authors: Kenta Nakagawa; Toru Asahi
Journal: Sci Rep Date: 2019-12-05 Impact factor: 4.379

1 in total

Absolute chirality of the γ-polymorph of glycine: correlation of the absolute structure with the optical rotation.

1. Determination of the Faraday rotation perpendicular to the optical axis in uniaxial CeF3 crystal by using the Generalized-High Accuracy Universal Polarimeter.

1. Determination of the Faraday rotation perpendicular to the optical axis in uniaxial CeF₃ crystal by using the Generalized-High Accuracy Universal Polarimeter.