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Literature DB >> 22573110

Ruthenium(IV) porphyrin catalyzed phosphoramidation of aldehydes with phosphoryl azides as a nitrene source.

Wenbo Xiao¹, Cong-Ying Zhou, Chi-Ming Che.

Abstract

[Ru(IV)(por)Cl(2)] (por = porphyrin dianion) can efficiently catalyze nitrene insertion into aldehyde C-H bonds with phosphoryl azides as a nitrene source to give N-acylphosphoramidates in good to high yields.

Entities: Chemical

Mesh：

Substances：

Year: 2012 PMID： 22573110 DOI： 10.1039/c2cc31686b

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

6 in total

1. Base-promoted direct amidation of esters: beyond the current scope and practical applications.

Authors: Ivaylo Slavchev; Jas S Ward; Kari Rissanen; Georgi M Dobrikov; Svilen Simeonov
Journal: RSC Adv Date: 2022-07-15 Impact factor: 4.036

2. Selective Radical Amination of Aldehydic C(sp²)-H Bonds with Fluoroaryl Azides via Co(II)-Based Metalloradical Catalysis: Synthesis of N-Fluoroaryl Amides from Aldehydes under Neutral and Nonoxidative Conditions.

Authors: Li-Mei Jin; Hongjian Lu; Yuan Cui; Christopher L Lizardi; Thiago N Arzua; Lukasz Wojtas; Xin Cui; X Peter Zhang
Journal: Chem Sci Date: 2014-06-01 Impact factor: 9.825

6. Synthesis of chiral N-phosphoryl aziridines through enantioselective aziridination of alkenes with phosphoryl azide via Co(II)-based metalloradical catalysis.

Authors: Jingran Tao; Li-Mei Jin; X Peter Zhang
Journal: Beilstein J Org Chem Date: 2014-06-04 Impact factor: 2.883

6 in total

Ruthenium(IV) porphyrin catalyzed phosphoramidation of aldehydes with phosphoryl azides as a nitrene source.

1. Base-promoted direct amidation of esters: beyond the current scope and practical applications.

2. Selective Radical Amination of Aldehydic C(sp²)-H Bonds with Fluoroaryl Azides via Co(II)-Based Metalloradical Catalysis: Synthesis of N-Fluoroaryl Amides from Aldehydes under Neutral and Nonoxidative Conditions.

3. O-Heterocycle Synthesis via Intramolecular C-H Alkoxylation Catalyzed by Iron Acetylacetonate.

Review 4. Opening up the Toolbox: Synthesis and Mechanisms of Phosphoramidates.

5. Transition-metal-free amination phosphoryl azide for the synthesis of phosphoramidates.

6. Synthesis of chiral N-phosphoryl aziridines through enantioselective aziridination of alkenes with phosphoryl azide via Co(II)-based metalloradical catalysis.

Ruthenium(IV) porphyrin catalyzed phosphoramidation of aldehydes with phosphoryl azides as a nitrene source.

1. Base-promoted direct amidation of esters: beyond the current scope and practical applications.

2. Selective Radical Amination of Aldehydic C(sp2)-H Bonds with Fluoroaryl Azides via Co(II)-Based Metalloradical Catalysis: Synthesis of N-Fluoroaryl Amides from Aldehydes under Neutral and Nonoxidative Conditions.

3. O-Heterocycle Synthesis via Intramolecular C-H Alkoxylation Catalyzed by Iron Acetylacetonate.

Review 4. Opening up the Toolbox: Synthesis and Mechanisms of Phosphoramidates.

5. Transition-metal-free amination phosphoryl azide for the synthesis of phosphoramidates.

6. Synthesis of chiral N-phosphoryl aziridines through enantioselective aziridination of alkenes with phosphoryl azide via Co(II)-based metalloradical catalysis.

2. Selective Radical Amination of Aldehydic C(sp²)-H Bonds with Fluoroaryl Azides via Co(II)-Based Metalloradical Catalysis: Synthesis of N-Fluoroaryl Amides from Aldehydes under Neutral and Nonoxidative Conditions.