Literature DB >> 22565863

A cyclic diaminocarbene with a pyramidalized nitrogen atom: a stable N-heterocyclic carbene with enhanced electrophilicity.

David Martin1, Nicolas Lassauque, Bruno Donnadieu, Guy Bertrand.   

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Year:  2012        PMID： 22565863      PMCID： PMC3374898          DOI： 10.1002/anie.201202137

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


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  22 in total

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4.  pKas of the conjugate acids of N-heterocyclic carbenes in water.

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9.  Synthetic routes to N-heterocyclic carbene precursors.

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10.  When does carbonylation of carbenes yield ketenes? A theoretical study with implications for synthesis.

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4.  Direct estimate of the internal π-donation to the carbene centre within N-heterocyclic carbenes and related molecules.

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5.  Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system.

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6.  Revealing the unusual role of bases in activation/deactivation of catalytic systems: O-NHC coupling in M/NHC catalysis.

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7.  Friedel-Crafts Reaction of N,N-Dimethylaniline with Alkenes Catalyzed by Cyclic Diaminocarbene-Gold(I) Complex.

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  7 in total

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