Literature DB >> 22559911

Synthesis, shape control, and methanol electro-oxidation properties of Pt-Zn alloy and Pt3Zn intermetallic nanocrystals.

Yijin Kang1, Jun Beom Pyo, Xingchen Ye, Thomas R Gordon, Christopher B Murray.   

Abstract

We report the first synthesis of highly monodisperse Pt(3)Zn nanocrystals (NCs). Shape-controlled synthesis generates cubic and spherical Pt-Zn NCs. Reaction temperature is the key to incorporate Zn into Pt, even in the absence of a strong reducing agent. The Pt-Zn NCs are active toward methanol oxidation, with the spherical NCs exhibiting higher activity than the cubic NCs. The Pt-Zn alloy phase can be transformed into the Pt(3)Zn intermetallic phase, upon annealing. The intermetallic Pt(3)Zn shows better performance than the alloy phase Pt-Zn. Besides the activity toward methanol oxidation, Pt-Zn NCs show excellent poisoning tolerance. With activities comparable to the commercial Pt catalyst, enhanced poisoning tolerance and lower cost, Pt-Zn and Pt(3)Zn NCs are a promising new family of catalysts for direct methanol fuel cells.

Entities:  

Mesh：

Substances：

Year:  2012        PMID： 22559911     DOI： 10.1021/nn301583g

Source DB:  PubMed          Journal:  ACS Nano        ISSN： 1936-0851            Impact factor:   15.881


  8 in total

Review 1.  A comprehensive and critical review of the recent progress in electrocatalysts for the ethanol oxidation reaction.

Authors:  Lubna Yaqoob; Tayyaba Noor; Naseem Iqbal
Journal:  RSC Adv       Date:  2021-05-06       Impact factor: 4.036

2.  N-doped TiO₂ Nanotubes as an Effective Additive to Improve the Catalytic Capability of Methanol Oxidation for Pt/Graphene Nanocomposites.

Authors:  Xiaohua Wang; Yueming Li; Shimin Liu; Long Zhang
Journal:  Nanomaterials (Basel)       Date:  2016-02-26       Impact factor: 5.076

3.  Synthesis of Hollow Pt-Ni Nanoboxes for Highly Efficient Methanol Oxidation.

Authors:  Rabia Jamil; Manzar Sohail; Nadeem Baig; Muhammad S Ansari; Riaz Ahmed
Journal:  Sci Rep       Date:  2019-10-24       Impact factor: 4.379

4.  Tuning Surface Structure of Pd3Pb/Pt n Pb Nanocrystals for Boosting the Methanol Oxidation Reaction.

Authors:  Xingqiao Wu; Yi Jiang; Yucong Yan; Xiao Li; Sai Luo; Jingbo Huang; Junjie Li; Rong Shen; Deren Yang; Hui Zhang
Journal:  Adv Sci (Weinh)       Date:  2019-10-29       Impact factor: 16.806

Review 5.  Noble Metal-Based Multimetallic Nanoparticles for Electrocatalytic Applications.

Authors:  Hyunjoong Kim; Tae Yong Yoo; Megalamane S Bootharaju; Jeong Hyun Kim; Dong Young Chung; Taeghwan Hyeon
Journal:  Adv Sci (Weinh)       Date:  2021-11-17       Impact factor: 16.806

6.  The mechanism of Co oxyhydroxide nano-islands deposited on a Pt surface to promote the oxygen reduction reaction at the cathode of fuel cells.

Authors:  Jinghao Lu; Libin Yang; Wei Guo; Songtao Xiao; Lingyu Wang; Yinggen OuYang; Peng Gao
Journal:  RSC Adv       Date:  2020-12-17       Impact factor: 4.036

7.  Formation of Pt-Zn Alloy Nanoparticles by Electron-Beam Irradiation of Wurtzite ZnO in the TEM.

Authors:  Sung Bo Lee; Jucheol Park; Peter A van Aken
Journal:  Nanoscale Res Lett       Date:  2016-07-20       Impact factor: 4.703

Review 8.  Nanostructure Optimization of Platinum-Based Nanomaterials for Catalytic Applications.

Authors:  Sibin Duan; Zhe Du; Hongsheng Fan; Rongming Wang
Journal:  Nanomaterials (Basel)       Date:  2018-11-17       Impact factor: 5.076
  8 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.