Literature DB >> 22551057

Mineralization of gaseous acetaldehyde by electrochemically generated Co(III) in H2SO4 with wet scrubber combinatorial system.

Muthuraman Govindan1, Sang-Joon Chung, Il-Shik Moon.   

Abstract

Electrochemically generated Co(III) mediated catalytic room temperature incineration of acetaldehyde, which is one of volatile organic compounds (VOCs), combined with wet scrubbing system was developed and investigated. Depending on the electrolyte's type, absorption come removal efficiency is varied. In presence of electrogenerated Co(III) in sulfuric acid, acetaldehyde was mineralized to CO2 and not like only absorption in pure sulfuric acid. The Co(III) mediated catalytic incineration led to oxidative absorption and elimination to CO2, which was evidenced with titration, CO2, and cyclic voltammetric analyses. Experimental conditions, such as current density, concentration of mediator, and gas molar flow rate were optimized. By the optimization of the experimental conditions, the complete mineralization of acetaldehyde was realized at a room temperature using electrochemically generated Co(III) with wet scrubber combinatorial system.

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Year:  2012        PMID: 22551057     DOI: 10.1021/co300012a

Source DB:  PubMed          Journal:  ACS Comb Sci        ISSN: 2156-8944            Impact factor:   3.784


  1 in total

1.  Implementation of concurrent electrolytic generation of two homogeneous mediators under widened potential conditions to facilitate removal of air-pollutants.

Authors:  Muthuraman Govindan; Alan M Bond; Il-Shik Moon
Journal:  Sci Rep       Date:  2017-02-13       Impact factor: 4.379

  1 in total

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