Literature DB >> 22544080

Asymmetric H-D exchange reactions of fluorinated aromatic ketones.

Yujun Zhao1, Xiaozhi Lim, Yuanhang Pan, Lili Zong, Wei Feng, Choon-Hong Tan, Kuo-Wei Huang.   

Abstract

Chiral bicyclic guanidine catalyzes the asymmetric H-D exchange reactions. Up to 30% ee was achieved. DFT calculations were employed to elucidate and explain the origin of the reaction's stereoselectivity.

Entities:  

Year:  2012        PMID： 22544080     DOI： 10.1039/c2cc31443f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  B(C6F5)3-Catalyzed α-Deuteration of Bioactive Carbonyl Compounds with D2O.

Authors:  Yejin Chang; Tanner Myers; Masayuki Wasa
Journal:  Adv Synth Catal       Date:  2019-11-26       Impact factor: 5.837

2.  Catalytic asymmetric synthesis of enantioenriched α-deuterated pyrrolidine derivatives.

Authors:  Xin Chang; Xiang Cheng; Chun-Jiang Wang
Journal:  Chem Sci       Date:  2022-03-17       Impact factor: 9.825

3.  Phosphorus pentoxide as a cost-effective, metal-free catalyst for ring opening polymerization of ε-caprolactone.

Authors:  Ismail Adoumaz; El Hassan Boutriouia; Redouane Beniazza; Hicham Qayouh; Abdelkrim El Kadib; Abdel Khoukh; Maud Save; Mohammed Lahcini
Journal:  RSC Adv       Date:  2020-06-19       Impact factor: 4.036
  3 in total

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