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Literature DB >> 22543407

Trichlorosilyl triflate-mediated enantioselective directed cross-aldol reaction between ketones using a chiral phosphine oxide as an organocatalyst.

Shohei Aoki¹, Shunsuke Kotani, Masaharu Sugiura, Makoto Nakajima.

Abstract

Trichlorosilyl triflate-promoted directed cross-aldol reaction between ketones in the presence of a chiral phosphine oxide as an organocatalyst is described. This is the first enantioselective cross-aldol reaction between simple ketones with good enantioselectivity.

Entities: Chemical

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Year: 2012 PMID： 22543407 DOI： 10.1039/c2cc31543b

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

1 in total

1. Rational Design of New Dihydrobenzooxophosphole-Based Lewis Base Organocatalysts.

Authors: Bo Qu; Lalith P Samankumara; Anjan Saha; Mac G Schumer; Zhengxu S Han; Nizar Haddad; Carl A Busacca; Nathan K Yee; Marisa C Kozlowski; Jinghua J Song; Chris H Senanayake
Journal: Synlett Date: 2020-04 Impact factor: 2.454

1 in total