Literature DB >> 22543307

Deca-heterosubstituted corannulenes.

Alla Pogoreltsev1, Ephrath Solel, Doron Pappo, Ehud Keinan.   

Abstract

The Cu(I)-catalyzed Ullmann condensation reaction between aliphatic alcohols and sym-pentachlorocorannulene provides a convenient entry to 1,3,5,7,9-pentaalkoxycorannulenes. The latter are easily converted to novel deca-heterosubstituted derivatives, such as 1,3,5,7,9-penta-X-2,4,6,8,10-penta-Y-corannulenes by electrophilic aromatic substitution.

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Year:  2012        PMID: 22543307     DOI: 10.1039/c2cc31801f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Flat corannulene: when a transition state becomes a stable molecule.

Authors:  Ephrath Solel; Doron Pappo; Ofer Reany; Tom Mejuch; Renana Gershoni-Poranne; Mark Botoshansky; Amnon Stanger; Ehud Keinan
Journal:  Chem Sci       Date:  2020-10-22       Impact factor: 9.825

2.  Chemical mimicry of viral capsid self-assembly via corannulene-based pentatopic tectons.

Authors:  Yu-Sheng Chen; Ephrath Solel; Yi-Fan Huang; Chien-Lung Wang; Tsung-Han Tu; Ehud Keinan; Yi-Tsu Chan
Journal:  Nat Commun       Date:  2019-08-01       Impact factor: 14.919

  2 in total

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