Literature DB >> 22523745

Dinuclear single-molecule magnets with porphyrin-phthalocyanine mixed triple-decker ligand systems giving SAP and SP coordination polyhedra.

Shohei Sakaue1, Akira Fuyuhiro, Takamitsu Fukuda, Naoto Ishikawa.   

Abstract

Two terbium ions in a triple-decker complex (Pc)Tb(Pc)Tb(T(p-OMe)PP) (Pc = phthalocyaninato, T(p-OMe)PP = tetra-p-methoxyphenylporphyrinato) have shown sharply different magnetic behaviours depending on symmetry of the coordination polyhedron. The fast quantum tunnelling relaxation process in a square-prismatic site has been revealed to be hindered by magnetic-dipolar coupling between the f-electronic systems. This journal is © The Royal Society of Chemistry 2012

Entities:  

Year:  2012        PMID： 22523745     DOI： 10.1039/c2cc31125a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Molecular Orientation of a Terbium(III)-Phthalocyaninato Double-Decker Complex for Effective Suppression of Quantum Tunneling of the Magnetization.

Authors:  Tsutomu Yamabayashi; Keiichi Katoh; Brian K Breedlove; Masahiro Yamashita
Journal:  Molecules       Date:  2017-06-15       Impact factor: 4.411

2.  Symmetry of octa-coordination environment has a substantial influence on dinuclear TbIII triple-decker single-molecule magnets.

Authors:  Keiichi Katoh; Brian K Breedlove; Masahiro Yamashita
Journal:  Chem Sci       Date:  2016-03-29       Impact factor: 9.825
  2 in total

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