Literature DB >> 22506681

Palladium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzosiloles via enantioselective C-H bond functionalization.

Ryo Shintani1, Haruka Otomo, Kensuke Ota, Tamio Hayashi.   

Abstract

A Pd-catalyzed asymmetric synthesis of Si-stereogenic dibenzosiloles is developed through enantioselective C-H bond functionalization of prochiral 2-(arylsilyl)aryl triflates. High chemo- and enantioselectivities are achieved by employing a Josiphos-type ligand under mild conditions.
© 2012 American Chemical Society

Entities:  

Year:  2012        PMID： 22506681     DOI： 10.1021/ja302278s

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  8 in total

1.  Enantioselective γ-C(sp3)-H Activation of Alkyl Amines via Pd(II)/Pd(0) Catalysis.

Authors:  Qian Shao; Qing-Feng Wu; Jian He; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2018-04-11       Impact factor: 15.419

2.  C-H bond activation enables the rapid construction and late-stage diversification of functional molecules.

Authors:  Joanna Wencel-Delord; Frank Glorius
Journal:  Nat Chem       Date:  2013-05       Impact factor: 24.427

3.  Enantioselective remote meta-C-H arylation and alkylation via a chiral transient mediator.

Authors:  Hang Shi; Alastair N Herron; Ying Shao; Qian Shao; Jin-Quan Yu
Journal:  Nature       Date:  2018-06-18       Impact factor: 49.962

4.  Enantioselective ortho-C-H cross-coupling of diarylmethylamines with organoborons.

Authors:  Brian N Laforteza; Kelvin S L Chan; Jin-Quan Yu
Journal:  Angew Chem Int Ed Engl       Date:  2015-08-04       Impact factor: 15.336

5.  Pd(II)-catalyzed enantioselective C-H activation/C-O bond formation: synthesis of chiral benzofuranones.

Authors:  Xiu-Fen Cheng; Yan Li; Yi-Ming Su; Feng Yin; Jian-Yong Wang; Jie Sheng; Harit U Vora; Xi-Sheng Wang; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2013-01-14       Impact factor: 15.419

6.  Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic silicon-bridged arylpyridinones.

Authors:  Ryo Shintani; Ryo Takano; Kyoko Nozaki
Journal:  Chem Sci       Date:  2015-11-09       Impact factor: 9.825

7.  Intramolecular Chain Hydrosilylation of Alkynylphenylsilanes Using a Silyl Cation as a Chain Carrier.

Authors:  Hidekazu Arii; Kenichi Nakabayashi; Kunio Mochida; Takayuki Kawashima
Journal:  Molecules       Date:  2016-08-01       Impact factor: 4.411

8.  Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes via chirality transfer from silicon to carbon.

Authors:  Ya Wu; Hua Chen; Wenyu Yang; Yu Fan; Lu Gao; Zhishan Su; Changwei Hu; Zhenlei Song
Journal:  RSC Adv       Date:  2019-08-21       Impact factor: 4.036
  8 in total

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