Literature DB >> 22499553

Catalytic air oxidation of biomass-derived carbohydrates to formic acid.

Jiang Li1, Dao-Jun Ding, Li Deng, Qing-Xiang Guo, Yao Fu.   

Abstract

An efficient catalytic system for biomass oxidation to form formic acid was developed. The conversion of glucose to formic acid can reach up to 52% yield within 3 h when catalyzed by 5 mol% of H(5)PV(2)Mo(10)O(40) at only 373 K using air as the oxidant. Furthermore, the heteropolyacid can be used as a bifunctional catalyst in the conversion of cellulose to formic acid (yield=35%) with air as the oxidant.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID： 22499553     DOI： 10.1002/cssc.201100466

Source DB:  PubMed          Journal:  ChemSusChem        ISSN： 1864-5631            Impact factor:   8.928


  3 in total

1.  Combining autoclave and LCWM reactor studies to shed light on the kinetics of glucose oxidation catalyzed by doped molybdenum-based heteropoly acids.

Authors:  Dorothea Voß; Sebastian Ponce; Stefanie Wesinger; Bastian J M Etzold; Jakob Albert
Journal:  RSC Adv       Date:  2019-09-17       Impact factor: 3.361

2.  One-pot synthesis of formic acid via hydrolysis-oxidation of potato starch in the presence of cesium salts of heteropoly acid catalysts.

Authors:  Nikolay V Gromov; Tatiana B Medvedeva; Yulia A Rodikova; Dmitrii E Babushkin; Valentina N Panchenko; Maria N Timofeeva; Elena G Zhizhina; Oxana P Taran; Valentin N Parmon
Journal:  RSC Adv       Date:  2020-08-04       Impact factor: 3.361

3.  Oxidative Conversion of Glucose to Formic Acid as a Renewable Hydrogen Source Using an Abundant Solid Base Catalyst.

Authors:  Atsushi Takagaki; Wataru Obata; Tatsumi Ishihara
Journal:  ChemistryOpen       Date:  2021-07-08       Impact factor: 2.630
  3 in total

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