Literature DB >> 22498915

Palladium-catalyzed monoselective C-H borylation of acetanilides under acidic conditions.

Bin Xiao1, Yi-Ming Li, Zhao-Jing Liu, Han-Yi Yang, Yao Fu.   

Abstract

A practical Pd-catalyzed reaction was developed to achieve C-H activation/C-B cross-coupling of acetanilides under acidic conditions. The new reaction shows a good functional group tolerance and an exclusive mono-selectivity. This C-H borylation method may provide a generally applicable route for the conversion of C-H moieties into many other types of bonds. This journal is © The Royal Society of Chemistry 2012

Entities:  

Year:  2012        PMID： 22498915     DOI： 10.1039/c2cc31737k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Palladium-catalyzed borylation of primary alkyl bromides.

Authors:  Amruta Joshi-Pangu; Xinghua Ma; Mohamed Diane; Sidra Iqbal; Robert J Kribs; Richard Huang; Chao-Yuan Wang; Mark R Biscoe
Journal:  J Org Chem       Date:  2012-07-23       Impact factor: 4.354

2.  Outer-sphere direction in iridium C-H borylation.

Authors:  Philipp C Roosen; Venkata A Kallepalli; Buddhadeb Chattopadhyay; Daniel A Singleton; Robert E Maleczka; Milton R Smith
Journal:  J Am Chem Soc       Date:  2012-07-03       Impact factor: 15.419

3.  Development of Cobalt Catalysts for the meta-Selective C(sp2)-H Borylation of Fluorinated Arenes.

Authors:  Tyler P Pabst; Paul J Chirik
Journal:  J Am Chem Soc       Date:  2022-04-02       Impact factor: 16.383

4.  Ligand-Promoted Borylation of C(sp(3))-H Bonds with Palladium(II) Catalysts.

Authors:  Jian He; Heng Jiang; Ryosuke Takise; Ru-Yi Zhu; Gang Chen; Hui-Xiong Dai; T G Murali Dhar; Jun Shi; Hao Zhang; Peter T W Cheng; Jin-Quan Yu
Journal:  Angew Chem Int Ed Engl       Date:  2015-11-27       Impact factor: 15.336

5.  Mechanistic Origins of Regioselectivity in Cobalt-Catalyzed C(sp2)-H Borylation of Benzoate Esters and Arylboronate Esters.

Authors:  Tyler P Pabst; Linda Quach; Kaitlyn T MacMillan; Paul J Chirik
Journal:  Chem       Date:  2020-12-09       Impact factor: 22.804

6.  Control of selectivity in palladium-catalyzed oxidative carbocyclization/borylation of allenynes.

Authors:  Youqian Deng; Teresa Bartholomeyzik; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2013-05-17       Impact factor: 15.336
  6 in total

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