Literature DB >> 22498907

Selective iron-catalyzed transfer hydrogenation of terminal alkynes.

Gerrit Wienhöfer1, Felix A Westerhaus, Rajenahally V Jagadeesh, Kathrin Junge, Henrik Junge, Matthias Beller.   

Abstract

A novel iron-catalyzed transfer hydrogenation of alkynes to the corresponding alkenes applying formic acid as a hydrogen donor is reported. An in situ combination of Fe(BF(4))(2)·6H(2)O and tetraphos allows for highly selective hydrogenation of a broad range of aromatic and aliphatic alkynes tolerating different functional groups. This journal is © The Royal Society of Chemistry 2012

Entities:  

Year:  2012        PMID： 22498907     DOI： 10.1039/c2cc31091k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Dehydrogenation, disproportionation and transfer hydrogenation reactions of formic acid catalyzed by molybdenum hydride compounds.

Authors:  Michelle C Neary; Gerard Parkin
Journal:  Chem Sci       Date:  2015-01-14       Impact factor: 9.825

2.  Nickel-Catalyzed Stereodivergent Synthesis of E- and Z-Alkenes by Hydrogenation of Alkynes.

Authors:  Kathiravan Murugesan; Charles Beromeo Bheeter; Pim R Linnebank; Anke Spannenberg; Joost N H Reek; Rajenahally V Jagadeesh; Matthias Beller
Journal:  ChemSusChem       Date:  2019-06-18       Impact factor: 8.928

3.  Ligand-Promoted Iridium-Catalyzed Transfer Hydrogenation of Terminal Alkynes with Ethanol and Its Application.

Authors:  Chengniu Wang; Shengnan Gong; Zhipeng Liang; Yufeng Sun; Rui Cheng; Banghua Yang; Yirong Liu; Jinfei Yang; Fei Sun
Journal:  ACS Omega       Date:  2019-09-18

4.  E-Selective Manganese-Catalyzed Semihydrogenation of Alkynes with H2 Directly Employed or In Situ-Generated.

Authors:  Ronald A Farrar-Tobar; Stefan Weber; Zita Csendes; Antonio Ammaturo; Sarah Fleissner; Helmuth Hoffmann; Luis F Veiros; Karl Kirchner
Journal:  ACS Catal       Date:  2022-01-31       Impact factor: 13.084

5.  Palladium-catalyzed hydroalkylation of methylenecyclopropanes with simple hydrazones.

Authors:  Jinzhong Yao; Zhangpei Chen; Lin Yu; Leiyang Lv; Dawei Cao; Chao-Jun Li
Journal:  Chem Sci       Date:  2020-05-15       Impact factor: 9.825
  5 in total

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