Literature DB >> 22492683

Structural and mechanistic revelations on an iron conversion reaction from pair distribution function analysis.

Badri Shyam1, Karena W Chapman, Mahalingam Balasubramanian, Robert J Klingler, George Srajer, Peter J Chupas.   

Abstract

Not simply small particles: pair distribution function analysis yields comprehensive insights into the electrochemical reaction of α-Fe(2)O(3) with lithium. The metallic Fe formed in this reaction was found to be defect-rich nanoparticles that restructure continuously without growing-an unusual characteristic likely linked to its highly reversible capacity.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID: 22492683     DOI: 10.1002/anie.201200244

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  6 in total

1.  Tracking lithium transport and electrochemical reactions in nanoparticles.

Authors:  Feng Wang; Hui-Chia Yu; Min-Hua Chen; Lijun Wu; Nathalie Pereira; Katsuyo Thornton; Anton Van der Ven; Yimei Zhu; Glenn G Amatucci; Jason Graetz
Journal:  Nat Commun       Date:  2012       Impact factor: 14.919

2.  Lithium Insertion Mechanism in Iron-Based Oxyfluorides with Anionic Vacancies Probed by PDF Analysis.

Authors:  Damien Dambournet; Karena W Chapman; Mathieu Duttine; Olaf Borkiewicz; Peter J Chupas; Henri Groult
Journal:  ChemistryOpen       Date:  2015-06-25       Impact factor: 2.911

3.  Asymmetric pathways in the electrochemical conversion reaction of NiO as battery electrode with high storage capacity.

Authors:  Ulrike Boesenberg; Matthew A Marcus; Alpesh K Shukla; Tanghong Yi; Eamon McDermott; Pei Fen Teh; Madhavi Srinivasan; Alexander Moewes; Jordi Cabana
Journal:  Sci Rep       Date:  2014-11-20       Impact factor: 4.379

4.  Non-equilibrium metal oxides via reconversion chemistry in lithium-ion batteries.

Authors:  Xiao Hua; Phoebe K Allan; Chen Gong; Philip A Chater; Ella M Schmidt; Harry S Geddes; Alex W Robertson; Peter G Bruce; Andrew L Goodwin
Journal:  Nat Commun       Date:  2021-01-25       Impact factor: 14.919

Review 5.  There's no place like real-space: elucidating size-dependent atomic structure of nanomaterials using pair distribution function analysis.

Authors:  Troels Lindahl Christiansen; Susan R Cooper; Kirsten M Ø Jensen
Journal:  Nanoscale Adv       Date:  2020-05-06

6.  Tracking Sodium-Antimonide Phase Transformations in Sodium-Ion Anodes: Insights from Operando Pair Distribution Function Analysis and Solid-State NMR Spectroscopy.

Authors:  Phoebe K Allan; John M Griffin; Ali Darwiche; Olaf J Borkiewicz; Kamila M Wiaderek; Karena W Chapman; Andrew J Morris; Peter J Chupas; Laure Monconduit; Clare P Grey
Journal:  J Am Chem Soc       Date:  2016-02-15       Impact factor: 15.419

  6 in total

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