Literature DB >> 22492671

A buckybowl with a lot of potential: C5-C20H5(CF3)5.

Igor V Kuvychko1, Sarah N Spisak, Yu-Sheng Chen, Alexey A Popov, Marina A Petrukhina, Steven H Strauss, Olga V Boltalina.   

Abstract

Lots of potential: a trifluoromethylated corannulene, C(5)-C(20)H(5)(CF(3))(5), has been prepared and characterized spectroscopically and by X-ray crystallography. The structure exhibits a highly ordered bowl stacking that is unusual for corannulenes with acyclic substituents. The first reduction of C(5)-C(20)H(5)(CF(3))(5) is anodically shifted by 0.95 V, making it the strongest corannulene-based electron acceptor to date.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 22492671     DOI： 10.1002/anie.201200178

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  2 in total

1.  (19)F NMR-, ESR-, and vis-NIR-spectroelectrochemical study of the unconventional reduction behaviour of a perfluoroalkylated fullerene: dimerization of the C70(CF3)10(-) radical anion.

Authors:  Michal Zalibera; Peter Machata; Tyler T Clikeman; Marco Rosenkranz; Steven H Strauss; Olga V Boltalina; Alexey A Popov
Journal:  Analyst       Date:  2015-11-07       Impact factor: 4.616

2.  Hierarchical Corannulene-Based Materials: Energy Transfer and Solid-State Photophysics.

Authors:  Allison M Rice; W Brett Fellows; Ekaterina A Dolgopolova; Andrew B Greytak; Aaron K Vannucci; Mark D Smith; Stavros G Karakalos; Jeanette A Krause; Stanislav M Avdoshenko; Alexey A Popov; Natalia B Shustova
Journal:  Angew Chem Int Ed Engl       Date:  2017-03-23       Impact factor: 15.336
  2 in total

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